Evidence map›Paper›PMID 40116051›Full record

ArticleInorganic chemistry2025

Enhancing the Stability and Catalytic Performance of Gold Subnanoclusters Mediated by Au···H-C Hydrogen Bonding and Au···π Interactions.

Alba Sorroche, Miguel Monge, José María López-de-Luzuriaga

Abstract read
In one paragraph

Article in Inorganic chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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0citing papers in PubMed
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1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Alba SorrocheDepartamento de Química, Instituto de Investigación en Química de la Universidad de La Rioja (IQUR), Universidad de La Rioja, Complejo Científico-Tecnológico, 26006 Logroño, Spain.
Miguel MongeDepartamento de Química, Instituto de Investigación en Química de la Universidad de La Rioja (IQUR), Universidad de La Rioja, Complejo Científico-Tecnológico, 26006 Logroño, Spain.ORCID 0000-0002-9672-8279
José María López-de-LuzuriagaDepartamento de Química, Instituto de Investigación en Química de la Universidad de La Rioja (IQUR), Universidad de La Rioja, Complejo Científico-Tecnológico, 26006 Logroño, Spain.ORCID 0000-0001-5767-8734

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Gold subnanoclusters (AuSNCs) exhibit remarkable catalytic activity; however, their short-lived transient existence and strong tendency for self-aggregation remain disadvantageous for practical application. Considering that weak secondary interactions, such as Au···H-C or Au···π, could enhance the stability of the subnanocluster system, we have assessed their influence on the stabilization through a combination of experimental and computational analyses. We have evaluated the stabilization ability of different functional groups toward the AuSNCs system. Matrix-assisted laser desorption/ionization-time of flight (MALDI-TOF) experiments, density functional theory (DFT) calculations, and topological tools (QTAIM and NCI) provide decisive insights into the mechanism of stabilization of the short-lived AuSNCs species. Additionally, we extended the stabilization analysis to an application in catalysis. By conducting a complete NCI analysis of an optimized energy pathway, we demonstrate how an Au

Identifiers

PMID40116051
PMCPMC12179818

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.