Evidence map›Paper›PMID 40111169›Full record

ArticleJournal of the American Chemical Society2025

Ti-catalyzed 1,2-Diamination of Alkynes Using 1,1-Disubstituted Hydrazines.

Partha Sarathi Karmakar, Yuya Kakiuchi, Jaekwan Kim, Michael R Harris, Daniel N Huh, Alexander G Sell, Christophe Copéret, Ian A Tonks

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Partha Sarathi KarmakarDepartment of Chemistry, University of Minnesota-Twin Cities, Minneapolis, Minnesota 55455, United States.
Yuya KakiuchiDepartment of Chemistry and Applied Biosciences, ETH Zürich, Vladimir Prelog Weg 2, Zürich CH-8093, Switzerland.ORCID 0000-0001-5882-2320
Jaekwan KimDepartment of Chemistry, University of Minnesota-Twin Cities, Minneapolis, Minnesota 55455, United States.
Michael R HarrisDepartment of Chemistry, University of Minnesota-Twin Cities, Minneapolis, Minnesota 55455, United States.ORCID 0000-0002-2671-9019
Daniel N HuhDepartment of Chemistry, University of Minnesota-Twin Cities, Minneapolis, Minnesota 55455, United States.ORCID 0000-0001-7887-0856
Alexander G SellDepartment of Chemistry, University of Minnesota-Twin Cities, Minneapolis, Minnesota 55455, United States.
Christophe CopéretDepartment of Chemistry and Applied Biosciences, ETH Zürich, Vladimir Prelog Weg 2, Zürich CH-8093, Switzerland.ORCID 0000-0001-9660-3890
Ian A TonksDepartment of Chemistry, University of Minnesota-Twin Cities, Minneapolis, Minnesota 55455, United States.ORCID 0000-0001-8451-8875

Funding

Ti-Catalyzed Oxidative Amination ReactionsR35GM119457 · NIGMS · UNIVERSITY OF MINNESOTA · PI Ian Albert Tonks · 2016 to 2026
$4.4M
Upgrade of a 500 MHz NMR Spectrometer for Applications in Biomedical ResearchS10OD011952 · OD · UNIVERSITY OF MINNESOTA · PI HOYE, THOMAS R. · 2012 to 2012
$378k
NIGMS NIH HHS R35 GM119457NIH HHS S10 OD011952
6 · The paper itself

Abstract

Ti-catalyzed alkyne diamination and alkyne hydrohydrazination proceed through a common

Identifiers

PMID40111169
PMCPMC12035820

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.