ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2025
An Electrochemically-Driven Reconstruction Strategy to Realize Highly Crystalline Covalent Organic Frameworks for Enhanced Hydrogen Evolution Reaction.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Pre-catalysts for the hydrogen evolution reaction: from dynamic reconstruction to rational design.Chemical science · 2026Review
- Rational Design of Covalent Organic Frameworks for Oxygen Electrocatalysis: Recent Advances and Mechanistic Insights.Nano-micro letters · 2026Review
- An Electrochemically-Driven Reconstruction Strategy to Realize Highly Crystalline Covalent Organic Frameworks for Enhanced Hydrogen Evolution Reaction.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
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Authors and funding
10 authors.
Funding
Abstract
Developing diverse methods to approach highly crystalline covalent organic frameworks (COFs) for improvement of their electrocatalytic hydrogen evolution reaction (HER) activity is important but very challenging. Herein, for the first time, an electrochemically-driven reconstruction strategy is demonstrated to convert semi-polymerized low-crystalline COFs into highly crystalline, structurally ordered COFs with enhanced HER activity. In situ and ex situ characterizations reveal that cyclic voltammetry (CV) cycles can promote crystallinity, thereby leading to improved conductivity, increased active site density, and superior stability. As a result, the highly crystalline COF achieves low overpotentials of 103.6 and 219.4 mV at 10 and 50 mA cm
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