ArticleTurkish journal of chemistry2025
A new water-soluble silicon phthalocyanine that catalyzes the photodegradation of pollutant dyes.
Article in Turkish journal of chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The removal of color arising from water-soluble dyes in wastewaters is necessary to counter the threat to health. Because of the difficulty in elimination of these dyes by conventional methods, their photodegradation using photosensitizers such as phthalocyanines (Pcs) has been employed recently. When compared to peripherally substituted derivatives, silicon Pcs are reported to be more biocompatible with low toxicity. Thus a new silicon Pc substituted with two quaternized dimethylamino phenoxy units (compound 1) and its quaternized derivative (compound 2) were synthesized to test its photocatalytic ability employing the dyes methylene blue (MB), eosin B (EB), erythrosine (ERB), sulforhodamine B (SRB), and brilliant blue FCF (BRB), some of whose absorption bands overlap with those of Pcs. The overlapped absorption bands were split using first-order derivative UV-vis spectra. The photodegradation rates of BRB, MB, and ERB were 41%, 38%, and 29%, respectively, under 30-s short time irradiation in the presence of compound
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