ArticleChemical science2025
The role of surface deformation on responsivity of the pillared layer metal-organic framework DUT-8(Ni).
Article in Chemical science, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Crystallization-assisted water adsorption in amorphous molecular adsorbents.Nature communications · 2026Article
- Synthesis, Structure, Spectra, and Applications of Metal-Organic Frameworks: Basolite C-300.International journal of molecular sciences · 2025Review
- Pressure Sensitivity of UiO-66 Framework with Encapsulated Spin Probe: A Molecular Dynamics Study.Molecules (Basel, Switzerland) · 2025Article
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Authors and funding
21 authors.
Funding
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Abstract
A unique feature of flexible metal-organic frameworks (MOFs) is their ability to respond dynamically towards molecular stimuli by structural transitions, resulting in pore-opening and closing processes. One of the most intriguing modes is the "gating", where the material transforms from the dense to the porous state. The conditions required for the solid phase structural transition are controlled by the kinetic barriers, including nucleation of the new phase commencing on the crystallite's outer surface. Thus, surface deformation may influence the nucleation, enabling deliberate tailoring of the responsivity. In the present contribution, we investigate how chemical surface treatments (surface deformation) affect the gate opening characteristics of a typical representative of gate pressure MOFs, DUT-8(Ni) ([Ni
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