Evidence map›Paper›PMID 40102438›Full record

ArticleNature communications2025

Blue organic long-persistent luminescence via upconversion from charge-transfer to locally excited singlet state.

Zesen Lin, Jinting Ye, Shin Shinohara, Yuya Tanaka, Rengo Yoshioka, Chin-Yiu Chan, Yi-Ting Lee, Xun Tang, Kirill Mitrofanov, Kai Wang and 8 more

Abstract read
In one paragraph

Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.

0numbers the graph read from it
0cells of the map it votes in
9citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

9 citing papers in PubMed.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

18 authors.

Zesen LinOrganic Optoelectronics Unit, Okinawa Institute of Science and Technology Graduate University, 1919-1 Tancha, Onna-son, Okinawa, 904-0495, Japan. zs.lin@nus.edu.sg.ORCID http://orcid.org/0000-0003-3876-9221
Jinting YeInstitute of Functional Nano and Soft Materials (FUNSOM), Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, Box 33, 199 Ren'ai Rd, Suzhou Industrial Park, Suzhou, Jiangsu, 215123, P. R. China.
Shin ShinoharaGraduate School of Science and Engineering, Chiba University, Inage, Chiba, 263-8522, Japan.
Yuya TanakaGraduate School of Science and Technology, Gunma University, Kiryu, Gunma, 376-8515, Japan.ORCID http://orcid.org/0000-0001-7777-0239
Rengo YoshiokaOrganic Optoelectronics Unit, Okinawa Institute of Science and Technology Graduate University, 1919-1 Tancha, Onna-son, Okinawa, 904-0495, Japan.ORCID http://orcid.org/0000-0002-6380-4140
Chin-Yiu ChanCenter for Organic Photonics and Electronics Research, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395, Japan.ORCID http://orcid.org/0000-0001-7721-9244
Yi-Ting LeeCenter for Organic Photonics and Electronics Research, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395, Japan.
Xun TangCenter for Organic Photonics and Electronics Research, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395, Japan.
Kirill MitrofanovOrganic Optoelectronics Unit, Okinawa Institute of Science and Technology Graduate University, 1919-1 Tancha, Onna-son, Okinawa, 904-0495, Japan.
Kai WangInstitute of Functional Nano and Soft Materials (FUNSOM), Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, Box 33, 199 Ren'ai Rd, Suzhou Industrial Park, Suzhou, Jiangsu, 215123, P. R. China.ORCID http://orcid.org/0000-0002-9860-2282
Hayato OuchiOrganic Optoelectronics Unit, Okinawa Institute of Science and Technology Graduate University, 1919-1 Tancha, Onna-son, Okinawa, 904-0495, Japan.
Liliia MoshniahaOrganic Optoelectronics Unit, Okinawa Institute of Science and Technology Graduate University, 1919-1 Tancha, Onna-son, Okinawa, 904-0495, Japan.ORCID http://orcid.org/0000-0001-9538-178X
Yemineni S L V NarayanaOrganic Optoelectronics Unit, Okinawa Institute of Science and Technology Graduate University, 1919-1 Tancha, Onna-son, Okinawa, 904-0495, Japan.
Hisao IshiiGraduate School of Science and Engineering, Chiba University, Inage, Chiba, 263-8522, Japan.ORCID http://orcid.org/0000-0002-7584-2769
Xiao-Hong ZhangInstitute of Functional Nano and Soft Materials (FUNSOM), Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, Box 33, 199 Ren'ai Rd, Suzhou Industrial Park, Suzhou, Jiangsu, 215123, P. R. China.ORCID http://orcid.org/0000-0002-6732-2499
Chihaya AdachiCenter for Organic Photonics and Electronics Research, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395, Japan.ORCID http://orcid.org/0000-0001-6117-9604
Xian-Kai ChenInstitute of Functional Nano and Soft Materials (FUNSOM), Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, Box 33, 199 Ren'ai Rd, Suzhou Industrial Park, Suzhou, Jiangsu, 215123, P. R. China. xkchen@suda.edu.cn.ORCID http://orcid.org/0000-0002-8580-7246
Ryota KabeOrganic Optoelectronics Unit, Okinawa Institute of Science and Technology Graduate University, 1919-1 Tancha, Onna-son, Okinawa, 904-0495, Japan. ryota.kabe@oist.jp.ORCID http://orcid.org/0000-0002-3647-4262

Funding

MEXT | Japan Science and Technology Agency (JST) JPMJFR201HMEXT | Japan Society for the Promotion of Science (JSPS) JP21H02020
6 · The paper itself

Abstract

Long-persistent luminescence (LPL) materials have applications from safety signage to bioimaging; however, existing organic LPL (OLPL) systems do not align with human scotopic vision, which is sensitive to blue light. We present a strategy to blueshift the emissions in binary OLPL systems by upconverting the charge-transfer (CT) to a locally excited (LE) singlet state. Through rigorous steady-state and time-resolved photoluminescence spectroscopy and wavelength-resolved thermoluminescence measurements, we provide the direct experimental evidence for this upconversion in OLPL systems featuring small energy offsets between the lowest-energy CT and LE singlet states. These systems exhibited strong room temperature LPL, particularly when extrinsic electron traps are added. Importantly, the developed OLPL system achieved Class A (ISO 17398) LPL, matching well with human scotopic vision. The findings not only elucidate the role of small energy offsets in modulating LPL but also provide potential avenues for enhancing the efficiency and applicability of OLPL materials.

Identifiers

PMID40102438
PMCPMC11920369

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.