ArticleWater science and technology : a journal of the International Association on Water Pollution Research2025
Ternary micro-electrolysis filter media for efficient PFOA removal in water: synthesis, characterization, and performance study.
Article in Water science and technology : a journal of the International Association on Water Pollution Research, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
This study reports the preparation of granular ternary micro-electrolysis materials and their effectiveness in removing the emerging contaminant PFOA. Al/nZVI/C@F granules were synthesized using a liquid-phase reduction method combined with high-temperature calcination. By comparing the removal of methylene blue dye by granules, the optimum preparation conditions were determined as follows: Fe:C = 5:1, fly ash = 50%, calcination temperature = 800 °C, and holding time = 1 h. Static batch experiments revealed that under optimal conditions (PFOA concentration = 25 mg/L, solid-liquid ratio = 30 g/L, pH = 3, reaction temperature = 15 °C), Al/nZVI/C@F achieved a PFOA removal rate of 97.83%. The removal efficiency of Al/nZVI/C@F (93.90%) was significantly higher than that of commercial iron-carbon (12.75%). After 45 days of dynamic column experiments, the removal efficiency of nZVI/C@F and Al/nZVI/C@F for PFOA (50 mg/L) remained above 60%, demonstrating strong practical application potential. Further adsorption-desorption experiments revealed that nZVI/C@F and Al/nZVI/C@F primarily removed 50 mg/L PFOA through adsorption. For a lower PFOA concentration of 0.5 mg/L, the defluorination rates were 53.2% for nZVI/C@F and 68.9% for Al/nZVI/C@F. High-performance liquid chromatography-tandem mass spectrometry was used to analyze the intermediates formed during PFOA removal, leading to a proposed degradation pathway.
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