ArticleNature chemistry2025
Photoinduced stepwise charge hopping in π-stacked perylene bisimide donor-bridge-acceptor arrays.
Article in Nature chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- Photoinduced Accumulative Electron-Transfer Dynamics in Perylene Diimide Polymers as Photoredox Catalysts.JACS Au · 2026Article
- Controllable and Exceptionally Efficient Spin-Orbit Charge-Transfer Intersystem Crossing in Twisted π-Conjugated Perylene Bisimides for High-Performance Photochemical Applications.Angewandte Chemie (International ed. in English) · 2026Article
- Synergistic Donor-Acceptor Effect in Conductive Covalent Organic Frameworks of Polyphthalocyanines for Aqueous Zn-IAngewandte Chemie (International ed. in English) · 2026Article
- Spiro-Induced Strain as a Design Principle for Long-Lived Singlet Diradicals with π-Single Bond Character.The Journal of organic chemistry · 2026Article
- Supramolecular Modulation of Photoinduced Charge Transfer: Tuning Between Tunneling and Incoherent Hopping.Angewandte Chemie (International ed. in English) · 2026Article
- Excimer-mediated multiexciton generation in covalently linked cross foldamers of thiophene-fused perylene bisimides.Chemical science · 2026Article
- Design and synthesis of a tetraphenylethene-porphyrin hetero-faced molecular cage for photodynamic therapy.National science review · 2026Article
- Article
- Generating extended foldamer dye stacks and unravelling their evolving exciton dynamics.Nature chemistry · 2026Article
- Delocalization versus Coherence under Vibrational and Environmental Disorder in Photoexcited Supramolecular Aggregates.Journal of the American Chemical Society · 2026Article
- Crystallochromism: A Hybrid Model for the Spectral Properties of Quinacridone Polymorphs.Journal of chemical theory and computation · 2025Article
- Unraveling Pathway Complexity in the Supramolecular Polymerization of Z-Shaped Perylenediimides: From KineticJournal of the American Chemical Society · 2025Article
- Photoinduced stepwise charge hopping in π-stacked perylene bisimide donor-bridge-acceptor arrays.Nature chemistry · 2025Article
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Authors and funding
4 authors.
Funding
Abstract
The mechanistic understanding of light-driven charge separation and charge-carrier transport within the frameworks of π-conjugated molecules is imperative to mimic natural photosynthesis and derive synthetic materials for solar energy conversion. In this regard, since the late 1980s, the distance and solvent dependence of stepwise (incoherent) charge-carrier hopping versus single-step (coherent) superexchange transport (tunnelling) have been studied in detail. Here we introduce structurally highly defined cofacially stacked donor-acceptor perylene bisimide arrays, which offer a high resemblance to natural systems. Similarity is achieved through controlling energy and electron transfer processes via intermolecular interactions between the π-stacked perylene bisimide subunits. Selective excitation of the donor induces electron transfer to the acceptor unit in polar solvents, facilitated by a 'through-stack' wire-like charge hopping mechanism with a low attenuation factor β = 0.21 Å
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Registered trials
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