ArticleScience advances2025
Interlayer confinement toward short hydrogen bond network construction for fast hydroxide transport.
Article in Science advances, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Interfacial hydrogen transfer for heterogeneous catalysis.Nature reviews. Chemistry · 2026Review
- Nanostructured Ion Conductor Design for Highly Efficient Ion Transport.Small (Weinheim an der Bergstrasse, Germany) · 2026Review
- A Fixed-Charge Interphase Synchronizes Ion Transport to Suppress Space-Charge-Driven Inefficiency Under Nanoliter Confinement.Angewandte Chemie (International ed. in English) · 2026Article
- Hydrogen bond mediated oxidation enables sustained oxygen evolution at industrial current densities.Nature communications · 2026Article
- In Situ Probing of Electrochemical Hydrogen Evolution Reaction Intermediates: From Single-Crystal Models to Nano-Catalysts.Nano-micro letters · 2026Review
- Constructing Continuous Interlayer Hydrogen-Bond Network in Nanofluidic Clay Membranes for Fast Cation Conduction and Anti-Swelling Osmotic Energy Generators.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Redefining Separator Design and Water Activity for High-Energy Zinc Batteries Using Covalent Organic Framework.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Bismuth Silicate Catalyst for Efficient Electrocatalytic COAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
12 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Driven by boosting demands for sustainable energy, highly conductive hydroxide exchange membranes (HEMs) are urgently required in electrochemical conversion devices. The hydrogen bonds shorter than 2.5 angstrom are expected to accelerate the ion transport. However, short hydrogen bonds (SHBs) can hardly form naturally because of the electron-withdrawing capability of O atom, which impedes its applications in water-mediated ion transport. This work develops an interlayer confinement strategy to construct SHB networks in a two-dimensional (2D) nanocapillary assembled by bismuth oxyiodide (BiOI) nanosheets and boost the ionic conductivity of HEMs. With confined nanochannels and adjustable hydrophilic groups in BiOI-based HEMs, the number of SHBs increases by 12 times, creating a shortcut for the Grotthuss-type anion transport, which in turn affords a high ionic conductivity of 168 millisiemens per centimeter at 90°C, higher than polymeric HEM and 2D-based HEM. This work demonstrates the facile approach to generating SHB networks in 2D capillaries and opens a promising avenue to developing advanced HEMs.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.