ArticleACS sustainable chemistry & engineering2025
Thermoreversible Diels-Alder Cross-Linking of BHMF-Based Polyesters: Synthesis, Characterization and Rheology.
Article in ACS sustainable chemistry & engineering, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
3 citing papers in PubMed.
- Toward Cost-Effective and Sustainable Production of 2,5-Bis(hydroxymethyl)furan by an Engineered Alcohol Dehydrogenase EcYjgB.ChemSusChem · 2026Article
- Alternative Natural Rubber Cross-Linking Utilizing a Disulfide-Containing Bismaleimide.Polymers · 2025Article
- Regiochemical Control of Shape Morphing in Diels-Alder Covalent Adaptable Networks.ACS macro letters · 2025Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
9 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
2,5-Bis(hydroxymethyl)furan (BHMF)-based polyesters are an interesting new class of biobased and potentially biodegradable furanic polymers. However, their thermal properties are currently insufficient, making them unsuitable for potential applications as commodity plastics. To improve this, several polyesters were synthesized using an enzymatic bulk polymerization process with the monomers BHMF and aliphatic dimethyl esters of varying spacer lengths. The BHMF units were subsequently cross-linked with a biobased bismaleimide (BM-689) through a [4 + 2] cycloaddition reaction between the furan and maleimide groups. This approach clearly demonstrated that these furan-based polyesters can be thermoreversibly cross-linked using this bismaleimide. The use of different spacer lengths further allows the variation in relative reaction rates and affects the reversibility and reprocessability of the polymers. In situ
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.