ArticleAnalytical chemistry2025
ICPMS/MS with Benzene Vapor.
Article in Analytical chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Benzene vapor was introduced into the reaction cell of an inductively coupled plasma tandem mass spectrometer. By evaporating benzene into the helium supply of the octopole reaction cell, product ion spectra for plasma-based atomic and molecular ions were recorded. Based on these spectra, product ions for the separation of the atomic ions from spectral overlaps from isobaric or molecular ion interferents were selected. Background equivalent concentrations (BECs) or sensitivity ratios for analytes and interferents were compared to on-mass analyses without benzene addition. Depending on the analyte, up to 4 orders of magnitude improvement could be achieved. Specifically, the detection of S and Se could be improved substantially, and their BECs were reduced to the μg/L and ng/L ranges, respectively. The separation of isobaric Rb and Sr isotopes or of CeO
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