ArticleNature communications2025
Understanding capacity fading from structural degradation in Prussian blue analogues for wide-temperature sodium-ion cylindrical battery.
Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
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The trial behind it
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Who cites it
21 citing papers in PubMed.
- Functional binder engineering for Prussian blue analogue cathodes: mechanistic insights, cross-system inspiration, and design principles.Chemical science · 2026Review
- High Entropy Effect Induced In-situ Surface Hydroxylation for Robust Electro-assisted Uranium Mineralization from Real Nuclear Wastewater.Nature communications · 2026Article
- Rapid and Recyclable Synthesis of Prussian Blue Analogs by Enrichment Crystallization Strategy for Wide-Temperature Sodium-Ion Cylindrical Cells.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- In Situ Zn-Doped Prussian Blue Analogues as High-Rate Cathodes for Wide-Temperature Sodium-Ion Batteries.Small methods · 2026Article
- Solvent Engineering Enabled Fast Long-Range Ion Transport in Mn/Fe-Based Prussian Blue Analogues for High-Loading-Mass Zn-Ion Batteries.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Fluorine-free acetonitrile-based electrolytes with anion-reinforced solvation chemistry for sustainable sodium-ion full batteries.Nature communications · 2026Article
- Surface Gradient Doping Enables High-Capacity and Long-Life Manganese-Based Prussian Blue Cathodes for Sodium-Ion Batteries.Angewandte Chemie (International ed. in English) · 2026Article
- Unraveling Water-Defect Coupled Degradation via Deuterium Isotope Labeling in Prussian Blue Analogue Cathodes for Long-Life Sodium-Ion Batteries.Angewandte Chemie (International ed. in English) · 2026Article
- Unmasking the intrinsic mechanistic limits of manganese Prussian blue analogues in aqueous Zn-ion batteries.Chemical science · 2026Article
- Unlocking the capacity of Mn-based Prussian blue cathodes in capacitive deionization.Nature communications · 2026Article
- Ammonium-Anchored Mn-Based Prussian Blue Analogues via Hydrogen Bonding for Robust Sodim-Ion Battery Cathodes.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- In Situ Defect Healing Suppresses Mn Dissolution Chain Reactions in Aqueous Sodium-Ion Cathodes.Nano-micro letters · 2026Article
- Suppressing Surface Degradation in Na-Rich Prussian Blue Cathodes via Liquid-Phase Dehydration.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Orbital-level stabilization of Fe-N bonds in Prussian blue positive electrodes via alkali metal lattice engineering.Nature communications · 2026Article
- Anode-free solid-state sodium batteries: navigating the challenges toward high energy density.Chemical science · 2026Review
- Exploration of structural and electrochemical characterization of niobium substituted alpha NaScientific reports · 2026Article
- Prussian Blue Analog as a Functional Additive for Restoring Sulfide Solid Electrolytes: Enhancing Moisture Stability in All-Solid-State Batteries.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Synthesis of Large-Area 2D Prussian Blue as Ion-Transport Channels for Non-Volatile Memristors.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Robust Janus-faced quasi-solid-state honeycomb-mimicking electrolytes for the fast transport and adequate supply of sodium ions.Chemical science · 2026Article
- Prussian Blue Analogues for Non-Aqueous Sodium-Ion and Potassium-Ion Batteries: The Landscape From Lab-Scale Optimizations Toward Practical Applications.Small (Weinheim an der Bergstrasse, Germany) · 2026Review
Corrections and comments
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Authors and funding
15 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Low-cost Fe-based Prussian blue analogues often suffer from capacity degradation, resulting in continuous energy loss, impeding commercialization for practical sodium-ion batteries. The underlying cause of capacity decrease remains mysterious. Herein, we show that irreversible phase transitions, structural degradation, deactivation of surface redox centres, and dissolution of transition metal ions in Prussian blue analogues accumulate continuously during cycling. These undesirable changes are responsible for massive destruction of their morphology, leading to the capacity decay. A dual regulation strategy is applied to alleviate the above-mentioned problems of Prussian blue analogues. The designed 18650/33140 cylindrical cells using modified Prussian blue analogues and hard carbon display improved cycling stability and wide-temperature working performance (-40
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Registered trials
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