Characterization of Vegetable Oils for Direct Use in Polyurethane-Based Adhesives: Physicochemical and Compatibility Assessment.

This study evaluates the compatibility and innovative applications of unmodified vegetable oils, including rapeseed, sunflower, linseed, castor, and used cooking oils, in the production of sustainable polymeric materials, particularly polyurethane adhesives. Fatty acid composition was characterized using GC-MS, functional groups were identified by FTIR, and physicochemical properties, such as hydroxyl value, acid value, viscosity, and density, were measured using conventional analytical techniques. The results highlight significant differences in the properties of the oils, influencing their suitability for specific industrial applications. Castor oil, with its high ricinoleic acid content and hydroxyl value, was identified as the most suitable option for bio-based polyols and polyurethane production. Compatibility tests confirmed that unmodified oils can be effectively blended with polyols, ensuring stability and homogeneity without chemical modification. This approach simplifies production, reduces reliance on petrochemical feedstocks, and advances the development of environmentally friendly polyurethane adhesives. Future research will focus on optimizing formulations and assessing the long-term performance of adhesives incorporating unmodified vegetable oils.