Evidence map›Paper›PMID 40076057›Full record

ArticlePolymers2025

Tailoring Thermomechanical, Shape Memory and Self-Healing Properties of Furan-Based Polyketone via Diels-Alder Chemistry with Different Bismaleimide Crosslinkers.

Esteban Araya-Hermosilla, Marco Carlotti, Felipe Orozco, Guilherme Macedo R Lima, Rodrigo Araya-Hermosilla, Daniela E Ortega, Diego Cortés-Arriagada, Francesco Picchioni, Ranjita K Bose, Virgilio Mattoli and 1 more

Abstract read
In one paragraph

Article in Polymers, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Esteban Araya-HermosillaFacultad de Ciencias Físicas y Matemáticas, Departamento de Ingeniería Química, Biotecnología y Materiales, Universidad de Chile, Beauchef 851, Santiago 8370456, Chile.ORCID 0000-0003-4271-6886
Marco CarlottiDipartimento di Chimica e Chimica Industriale, Università di Pisa, Via Moruzzi 13, 56124 Pisa, Italy.ORCID 0000-0001-8086-7613
Felipe OrozcoDepartment of Chemical Product Engineering, ENTEG, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands.ORCID 0000-0002-3412-7654
Guilherme Macedo R LimaDepartment of Chemical Product Engineering, ENTEG, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands.ORCID 0000-0001-9363-8166
Rodrigo Araya-HermosillaInstituto Universitario de Investigación y Desarrollo Tecnológico (IDT), Universidad Tecnológica Metropolitana, Ignacio Valdivieso 2409, San Joaquín, Santiago 8940577, Chile.ORCID 0000-0003-3611-1733
Daniela E OrtegaCentro Integrativo de Biología y Química Aplicada (CIBQA), Facultad de Salud, Universidad Bernardo O'Higgins, General Gana 1702, Santiago 8370854, Chile.ORCID 0000-0002-0724-4206
Diego Cortés-ArriagadaInstituto Universitario de Investigación y Desarrollo Tecnológico (IDT), Universidad Tecnológica Metropolitana, Ignacio Valdivieso 2409, San Joaquín, Santiago 8940577, Chile.ORCID 0000-0002-6709-1723
Francesco PicchioniDepartment of Chemical Product Engineering, ENTEG, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands.ORCID 0000-0002-8232-2083
Ranjita K BoseDepartment of Chemical Product Engineering, ENTEG, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands.ORCID 0000-0003-1928-5264
Virgilio MattoliCenter for Materials Interfaces, Istituto Italiano di Tecnologia Viale Rinaldo Piaggio 34, 56025 Pontedera, PI, Italy.ORCID 0000-0002-4715-8353
Andrea PucciDipartimento di Chimica e Chimica Industriale, Università di Pisa, Via Moruzzi 13, 56124 Pisa, Italy.ORCID 0000-0003-1278-5004

Funding

Fondo Nacional de Desarrollo Científico y Tecnológico 3230016
6 · The paper itself

Abstract

Furan/maleimide dynamic covalent chemistry has been extensively used to fabricate re-workable and self-healing thermosets. Understanding the relationship between crosslinker structure, network dynamics, and material final properties, however, remains a challenge. This study introduces self-healing and shape-memory thermosets derived from furan-functionalized polyketones (PKFU) crosslinked with aromatic bis-maleimides, i.e., 1,1'-(methylenedi-4,1-phenylene)bis-maleimide (BISM1) and bis(3-ethyl-5-methyl-4-maleimidophenyl)methane (BISM2), via a thermally reversible Diels-Alder reaction. Polyketones were chemically modified with furfurylamine through the Paal-Knorr reaction, achieving varying furan grafting ratios. The resulting networks, characterized by ATR-FTIR,

Indexed as

Diels-Alder click chemistryPaal-Knorr reactionpolyketoneself-healingshape-memory polymers

Identifiers

PMID40076057
PMCPMC11902186

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.