Evidence map›Paper›PMID 40073289›Full record

ArticleAngewandte Chemie (International ed. in English)2025

Organic Room-Temperature near-IR Phosphorescence Harvested by Intramolecular Through-Space Sensitization in Composite Molecules.

Iida Partanen, Chao-Hsien Hsu, Emily Hsue-Chi Shi, Iván Maisuls, Toni Eskelinen, Antti J Karttunen, Jarkko J Saarinen, Cristian A Strassert, Andrey Belyaev, Pi-Tai Chou and 1 more

Abstract read
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In one paragraph

Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Iida Partanen *Department of Chemistry and Sustainable Technology, University of Eastern Finland, Yliopistokatu 7, Joensuu, 80101, Finland.
Chao-Hsien Hsu *Department of Chemistry, National Taiwan University, Taipei, Taiwan, 10617, China.
Emily Hsue-Chi ShiDepartment of Chemistry, National Taiwan University, Taipei, Taiwan, 10617, China.
Iván MaisulsInstitut für Anorganische und Analytische Chemie, Universität Münster, CiMIC, SoN, CeNTech, Heisenbergstraße 11, Münster, 48149, Germany.
Toni EskelinenDepartment of Chemistry and Materials Science, Aalto University, Aalto, FI-00076, Finland.
Antti J KarttunenDepartment of Chemistry and Materials Science, Aalto University, Aalto, FI-00076, Finland.
Jarkko J SaarinenDepartment of Chemistry and Sustainable Technology, University of Eastern Finland, Yliopistokatu 7, Joensuu, 80101, Finland.
Cristian A StrassertInstitut für Anorganische und Analytische Chemie, Universität Münster, CiMIC, SoN, CeNTech, Heisenbergstraße 11, Münster, 48149, Germany.
Andrey BelyaevDepartment of Chemistry and Sustainable Technology, University of Eastern Finland, Yliopistokatu 7, Joensuu, 80101, Finland.
Pi-Tai ChouDepartment of Chemistry, National Taiwan University, Taipei, Taiwan, 10617, China.
Igor O KoshevoyDepartment of Chemistry and Sustainable Technology, University of Eastern Finland, Yliopistokatu 7, Joensuu, 80101, Finland.

Funding

Academy of Finland 320166Academy of Finland 340584Academy of Finland 351618Academy of Finland 353123Deutsche ForschungsgemeinschaftNational Science and Technology Council NSTC-112-2639-M-002-007-ASP
6 · The paper itself

Abstract

A family of coordination compounds with short intramolecular spatial separation between an organic chromophore and a metal center was studied. The specific geometry was realized by means of anthracene-functionalized tertiary aryl phosphanes. Their silver and gold complexes (1, 2) operate as conventional fluorophores, with photophysical behavior defined by anthracene-localized allowed transitions. In contrast, bichromophoric species, containing phenyl bipyridine- (3, 5, 6, 8) or terpyridine- (4, 7) derived platinum(II) fragments, demonstrate fast intersystem crossing to the triplet state associated with the pincer metal component. Theoretical results corroborated that the short intramolecular distance between the platinum constituent and the adjacent anthracene facilitates subsequent through-space triplet (T

Indexed as

Energy transferNIR luminescenceOrganic phosphorescenceSensitizationThrough‐space interactions

Identifiers

PMID40073289
PMCPMC12176076

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.