ArticleAngewandte Chemie (International ed. in English)2025
Hydrogen-Bond-Directed Supramolecular Organic Semiconductor Thin Films Realized via Thermal Precursor Approach.
Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Nanoarchitectonics in Materials Science, Second Edition.Materials (Basel, Switzerland) · 2026Article
- Hydrogen-Bond-Directed Supramolecular Organic Semiconductor Thin Films Realized via Thermal Precursor Approach.Angewandte Chemie (International ed. in English) · 2025Article
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Authors and funding
8 authors.
Funding
Abstract
Flexible organic semiconductors are regarded as an important class of functional materials, enabling their fabrication via a solution-processed method. However, supramolecularly designed organic thin-film transistor (OTFT) devices using hydrogen bonds have not been sufficiently developed. This is because of the reduced solubility caused by introducing hydrogen bond sites and the difficulty in controlling molecular orientations and packing structures. Herein, we report a reasonable strategy for the formation of hydrogen-bonded semiconductor thin films of a tetrabenzoporphyrin derivative with amide groups using the thermal precursor approach. The thin films are successfully fabricated by thermal conversion of the corresponding precursor in the film state. Assembly structure with a hydrogen-bond network is revealed by the combination of X-ray diffraction and infrared p-polarized multiple-angle incidence resolution spectrometry. The OTFT devices exhibit high hole mobility of 0.25 cm
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