Evidence map›Paper›PMID 40050628›Full record

ArticleNature communications2025

The dynamics of plasmon-induced hot carrier creation in colloidal gold.

Anna Wach, Robert Bericat-Vadell, Camila Bacellar, Claudio Cirelli, Philip J M Johnson, Rebeca G Castillo, Vitor R Silveira, Peter Broqvist, Jolla Kullgren, Alexey Maximenko and 6 more

Erratum issuedAbstract read
In one paragraph

Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 8 papers.

0numbers the graph read from it
0cells of the map it votes in
8citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

8 citing papers in PubMed.

  1. Article
  2. Article
  3. Plasmonic Hot-Carrier Redox Enables Proton-Coupled Electron Transfer at C─H Bonds.Angewandte Chemie (International ed. in English) · 2026
    Article
  4. Article
  5. Article
  6. Article
  7. Article
  8. Article
4 · The record

Corrections and comments

5 · Who and what money

Authors and funding

16 authors.

Anna WachSOLARIS National Synchrotron Radiation Centre, Jagiellonian University, Krakow, Poland.ORCID http://orcid.org/0000-0003-3112-2759
Robert Bericat-VadellDepartment of Chemistry-Ångström, Physical Chemistry division, Uppsala University, Uppsala, Sweden.ORCID http://orcid.org/0000-0002-7208-0092
Camila BacellarPaul Scherrer Institut, Villigen PSI, Switzerland.ORCID http://orcid.org/0000-0003-2166-241X
Claudio CirelliPaul Scherrer Institut, Villigen PSI, Switzerland.ORCID http://orcid.org/0000-0003-4576-3805
Philip J M JohnsonPaul Scherrer Institut, Villigen PSI, Switzerland.ORCID http://orcid.org/0000-0002-7251-4815
Rebeca G CastilloMax Planck Institute for Chemical Energy Conversion, Mülheim an der Ruhr, Mülheim an der Ruhr, Germany.
Vitor R SilveiraDepartment of Chemistry-Ångström, Physical Chemistry division, Uppsala University, Uppsala, Sweden.ORCID http://orcid.org/0009-0002-3698-9896
Peter BroqvistMaxepartment of Chemistry-Ångström, Structural Chemistry division, Uppsala University, Uppsala, Sweden.ORCID http://orcid.org/0000-0002-9842-4332
Jolla KullgrenMaxepartment of Chemistry-Ångström, Structural Chemistry division, Uppsala University, Uppsala, Sweden.
Alexey MaximenkoSOLARIS National Synchrotron Radiation Centre, Jagiellonian University, Krakow, Poland.ORCID http://orcid.org/0000-0003-2660-8105
Tomasz SobolSOLARIS National Synchrotron Radiation Centre, Jagiellonian University, Krakow, Poland.ORCID http://orcid.org/0000-0002-9661-0932
Ewa Partyka-JankowskaSOLARIS National Synchrotron Radiation Centre, Jagiellonian University, Krakow, Poland.
Peter NordlanderDepartment of Electrical and Computer Engineering, Rice University, Houston, TX, USA.ORCID http://orcid.org/0000-0002-1633-2937
Naomi J HalasDepartment of Electrical and Computer Engineering, Rice University, Houston, TX, USA.ORCID http://orcid.org/0000-0002-8461-8494
Jakub SzlachetkoSOLARIS National Synchrotron Radiation Centre, Jagiellonian University, Krakow, Poland. jakub.szlachetko@uj.edu.pl.
Jacinto SáInstitute of Physical Chemistry, Polish Academy of Sciences, Warsaw, Poland. jacinto.sa@kemi.uu.se.ORCID http://orcid.org/0000-0003-2124-9510

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The generation and dynamics of plasmon-induced hot carriers in gold nanoparticles offer crucial insights into nonequilibrium states for energy applications, yet the underlying mechanisms remain experimentally elusive. Here, we leverage ultrafast X-ray absorption spectroscopy (XAS) to directly capture hot carrier dynamics with sub-50 fs temporal resolution, providing clear evidence of plasmon decay mechanisms. We observe the sequential processes of Landau damping (~25 fs) and hot carrier thermalization (~1.5 ps), identifying hot carrier formation as a significant decay pathway. Energy distribution measurements reveal carriers in non-Fermi-Dirac states persisting beyond 500 fs and observe electron populations exceeding single-photon excitation energy, indicating the role of an Auger heating mechanism alongside traditional impact excitation. These findings deepen the understanding of hot carrier behavior under localized surface plasmon resonance, offering valuable implications for applications in photocatalysis, photovoltaics, and phototherapy. This work establishes a methodological framework for studying hot carrier dynamics, opening avenues for optimizing energy transfer processes in nanoscale plasmonic systems.

Identifiers

PMID40050628
PMCPMC11885627

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.