ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2025
Perfluorinated Organosilicons Enabling Low-Loss Ferroelectric Polymer Composites for Efficient Energy Storage and Electroluminescence.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Organosilicon cluster goes ferroelectric.National science review · 2026Article
- Perfluorinated Organosilicons Enabling Low-Loss Ferroelectric Polymer Composites for Efficient Energy Storage and Electroluminescence.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
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Authors and funding
10 authors.
Funding
Abstract
Ferroelectric polymers for energy storage and conversions suffer from high energy losses. Despite great efforts in polymer composites with organic or inorganic fillers, limited successes are achieved with an often compromised dielectric constant (K). Here, a synthesized organic-inorganic hybrid-perfluorinated polyhedral oligomeric silsesquioxane (F-POSS) is presented for creating an ultralow-loss ferroelectric polymer composite. The incorporation of such perfluorinated organosilicons with unique "cage-arm" structure into the polymer not only modulates chain conformations but also inhibits charge transport through its wide bandgap and strong carrier-trapping capabilities. This results in a significant reduction of dielectric/conduction losses and enhanced electric breakdown strength while maintaining a high K, yielding a discharged energy density (U
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