ArticleNature communications2025
Dimensional evolution of charge mobility and porosity in covalent organic frameworks.
Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
7 citing papers in PubMed.
- High Charge Carrier Mobility in Non-Conjugated 3D Covalent Organic Frameworks.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Suppressed excitonic effects enable high mobility and high-yield photoconductivity in a pyridine-coordinated two-dimensional polymer crystal.Nature communications · 2026Article
- Modulation of 1D Ru-Porphyrin Biomimetic COF to Enhance Synergistic Dual C─H Bond Air Oxidation for Cyclohexenone Synthesis.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- From Metal-Centered Catalysis to Organic Orbital Programming in Photoelectrocatalysis.Advanced materials (Deerfield Beach, Fla.) · 2026Review
- Scalable Aqueous Polymerization Via Nanoconfinement Effect Generating Two-Dimensional Polymers With Excitation-Dependent Clusteroluminescence.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Polarized dislocation covalent organic frameworks ignite hot electrons to propel photocatalytic hydrogen generation.Nature communications · 2026Article
- Topology engineering of COFsChemical science · 2026Article
Corrections and comments
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Authors and funding
9 authors.
Funding
Abstract
Covalent organic frameworks are an emerging class of covalently linked polymers with programmable lattices and well-defined nanopores. Developing covalent organic frameworks with both high porosity and excellent charge transport properties is crucial for widespread applications, including sensing, catalysis, and organic electronics. However, achieving the combination of both features remains challenging due to the lack of overarching structure-property correlations. Here, we report a strategy toward covalent organic frameworks with tunable dimensionality. The concept relies on splicing one-dimensional charge-conducting channels to form extended networks with tailorable substitution patterns. Such dimensional evolution and substitution control enable fine-tuning of electronic band structure, charge mobility, and porosity. According to surface-area characterization, high-frequency terahertz photoconductivity measurements, and theoretical calculations, the transition from one-dimensional to para-linked two-dimensional networks furnishes a substantial increase in surface area and a decrease in local charge mobility. The latter feature is assigned to substitution-induced electronic band flattening. A subtle balance of surface area (947 m
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.