Evidence map›Paper›PMID 40025848›Full record

ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2025

Transformation of 3D Metal-Organic Frameworks into Nanosheets with Enhanced Memristive Behavior for Electronic Data Processing.

Yuri A Mezenov, Semyon V Bachinin, Yuliya A Kenzhebayeva, Anastasiia S Efimova, Pavel V Alekseevskiy, Daria Poloneeva, Anastasia Lubimova, Svyatoslav A Povarov, Vladimir Shirobokov, Mikhail S Dunaevskiy and 7 more

Erratum issuedAbstract read
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In one paragraph

Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

5 · Who and what money

Authors and funding

17 authors.

Yuri A MezenovQingdao Innovation and Development Center, Harbin Engineering University, Qingdao, Shandong, 266000, China.
Semyon V BachininSchool of Physics and Engineering, ITMO University, St. Petersburg, 197101, Russia.
Yuliya A KenzhebayevaSchool of Physics and Engineering, ITMO University, St. Petersburg, 197101, Russia.
Anastasiia S EfimovaSchool of Physics and Engineering, ITMO University, St. Petersburg, 197101, Russia.
Pavel V AlekseevskiySchool of Physics and Engineering, ITMO University, St. Petersburg, 197101, Russia.
Daria PoloneevaAdvanced Catalytic Materials (ACM), KAUST Catalysis Center (KCC), Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology, Thuwal, 23955, Saudi Arabia.
Anastasia LubimovaSchool of Physics and Engineering, ITMO University, St. Petersburg, 197101, Russia.
Svyatoslav A PovarovSchool of Physics and Engineering, ITMO University, St. Petersburg, 197101, Russia.
Vladimir ShirobokovSchool of Physics and Engineering, ITMO University, St. Petersburg, 197101, Russia.
Mikhail S DunaevskiySchool of Physics and Engineering, ITMO University, St. Petersburg, 197101, Russia.
Aleksandra S FalchevskayaITMO University, "Solution Chemistry of Advanced Materials and Technologies" (SCAMT) International Institute, Saint Petersburg, 191002, Russia.
Andrei S PotapovNikolaev Institute of Inorganic Chemistry Siberian Branch of the Russian Academy of Sciences, Laboratory of Metal-Organic Coordination Polymers, Novosibirsk, 630090, Russia.
Alexander NovikovSaint Petersburg State University, Saint Petersburg, 199034, Russia.
Artem A SelyutinSaint Petersburg State University, Saint Petersburg, 199034, Russia.
Pascal BouletInstitut Jean Lamour, Universit de Lorraine, UMR CNRS 7198, Nancy, 54011, France.
Alena N KulakovaSchool of Physics and Engineering, ITMO University, St. Petersburg, 197101, Russia.
Valentin A MilichkoSchool of Physics and Engineering, ITMO University, St. Petersburg, 197101, Russia.ORCID https://orcid.org/0000-0002-8461-0804

Funding

Priority 2030 Federal Academic Leadership ProgramRUDN University Scientific Projects Grant System 021342-2-000Russian Science Foundation 22-72-10027
6 · The paper itself

Abstract

The transition from three-dimensional (3D) to two-dimensional (2D) semiconducting and insulating materials for micro- and opto-electronics is driven by an energy efficiency and device miniaturization. Herein, the simplicity of growth and stacking of 2D metal-organic framework (MOF) with such planar devices opens up new perspectives in controlling their efficiency and operating parameters. Here, the study reports on 3D to 2D MOF' structural transformation to achieve ultrathin nanosheets with enhanced insulating properties. Based on neutral N-donor ligands, the study designs and solvothermally synthesizes 3D MOFs followed by their thermal and solvent treatment to implement the transformation. A set of single crystal and powder X-ray diffraction, electron microscopy, Raman spectroscopy, numerical modeling, and mechanical exfoliation confirm the nature of the transformation. Compared with initial 3D MOF, its nanosheets demonstrate sufficient changes in electronic properties, expressed as tuning their absorption, photoluminescence, and resistivity. The latter allows to demonstrate the prototype of ultrathin memristive element based on a 4 to 32 nm MOF nanosheet with enhanced functionality (150 to 1400 ON/OFF ratio, retention time exceeding 7300 s, and 100 cycles of switching), thereby, extending the list of scalable and insulating 2D MOFs for micro- and opto-electronics.

Indexed as

memristive behaviormetal–organic frameworksnanosheetsstructural transformation

Identifiers

PMID40025848
PMCPMC12021068

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.