Evidence map›Paper›PMID 40017779›Full record

ArticleJACS Au2025

A Spectroscopic Criterion for Identifying the Degree of Ground-Level Near-Degeneracy Derived from Effective Hamiltonian Analyses of Three-Coordinate Iron Complexes.

Wang Chen, Nikolai Kochetov, Thomas Lohmiller, Qing Liu, Liang Deng, Alexander Schnegg, Shengfa Ye

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in JACS Au, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Wang ChenState Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, China.
Nikolai KochetovEPR Research Group, Max Planck Institute for Chemical Energy Conversion, D-45470 Mülheim an der Ruhr, Germany.
Thomas LohmillerEPR4Energy Joint Lab, Department Spins in Energy Conversion and Quantum Information Science, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 12489 Berlin, Germany.ORCID https://orcid.org/0000-0003-0373-1506
Qing LiuState Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Shanghai 200032, China.
Liang DengState Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Shanghai 200032, China.ORCID https://orcid.org/0000-0002-0964-9426
Alexander SchneggEPR Research Group, Max Planck Institute for Chemical Energy Conversion, D-45470 Mülheim an der Ruhr, Germany.ORCID https://orcid.org/0000-0002-2362-0638
Shengfa YeState Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, China.ORCID https://orcid.org/0000-0001-9747-1412

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The fascinating magnetic and catalytic properties of coordinatively unsaturated 3d metal complexes are a manifestation of their electronic structures, in particular their nearly doubly or triply degenerate orbital ground levels. Here, we propose a criterion to determine the degree of degeneracy of this class of complexes based on their experimentally accessible magnetic anisotropy (parametrized by the electron spin

Identifiers

PMID40017779
PMCPMC11862956

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