ArticleJACS Au2025
Optical Axial Chirality Enhancement and Transfer within Aromatic Micelles upon (Co-)encapsulation.
Article in JACS Au, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Non-Covalent PL, CD, and CPL Activation of Linear Aromatic Oligomers within Axially Chiral Aromatic Capsules.Angewandte Chemie (International ed. in English) · 2026Article
- Aqueous Accumulation and Co-Accumulation of Multiple Cationic Porphyrins within a Polyaromatic Capsule.JACS Au · 2026Article
- Chiral Micellar Assemblies for Circularly Polarized Luminescence Amplification, Dye Encapsulation, and Multilevel Information Encryption.Angewandte Chemie (International ed. in English) · 2026Article
- Cavity Constriction and Chiralization of Polyaromatic Subnanotubes via Post-assembly Ligand/Metal Modification.Journal of the American Chemical Society · 2026Article
- Hybridized Host Functions in Polyaromatic Tube-in-Capsule Composites.Angewandte Chemie (International ed. in English) · 2026Article
- Chiral Aromatic Micelles as Chiroptical Host Tools for Large Metallodyes in Water.Journal of the American Chemical Society · 2025Article
Corrections and comments
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Authors and funding
9 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Axial chirality is the key physiochemical element, yet its chiroptical utilities have been largely limited to covalent synthesis and infinitely assembled systems so far. Here we report a new application of axially chiral binaphthyls for efficient, optical chirality enhancement and transfer upon noncovalent encapsulation by achiral aromatic micelles in water. The CD activities of dialkoxy binaphthyls are significantly enhanced (up to 7-fold) upon encapsulation by an anthracene-based aromatic micelle. Large emission enhancement (∼4-fold) and efficient guest-to-guest, optical chirality transfer are achieved through coencapsulation of the binaphthyls with achiral cycloparaphenylenes, in a guest-within-guest fashion, by the micelle. The observed unusual properties are derived from the tight inclusion of the chiral guests into the macrocyclic guests, efficiently generated only in the aromatic cavity. Moderate CPL can be observed from the coencapsulated macrocycles within the ternary composites. Furthermore, more than ∼4-fold enhanced guest-to-guest chiroptical transfer is demonstrated with a functionalized cycloparaphenylene through the present coencapsulation strategy.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.