ArticleJACS Au2025
Pairing Electrocatalytic Reduction and Oxidation of Biomass-Derived 5-Hydroxymethylfurfural into Highly Value-Added Chemicals.
Article in JACS Au, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
3 citing papers in PubMed.
- Modulating Ni-O-V Bridges in NiV-Layered Double Hydroxides Microspheres for Robust Electrocatalytic Coupling of 1,5-Pentanediol Oxidation and Nitrate Reduction.Angewandte Chemie (International ed. in English) · 2026Article
- Article
- Photoelectrochemical valorisation of organic waste for the cogeneration of solar fuels and value-added chemicals.Chemical science · 2025Review
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Authors and funding
8 authors.
Funding
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Abstract
Simultaneous electrocatalytic reduction and oxidation of 5-hydroxymethylfurfural (HMF) is crucial for biomass refineries. Herein, we report the unprecedentedly high efficiency of the nearly complete conversion of biomass-derived HMF to value-added products, achieving >95% selectivity at -0.4 V vs RHE by pairing electrocatalytic reduction and oxidation (PERO) reactions in a single electrochemical cell. At the cathode, we achieved 99% conversion of HMF to 2,5-dihydroxymethylfuran (DHMF) in ∼99% yield under mild conditions using a PtRu alloy. At the anode, we observed 99% conversion of HMF, nearly perfect selectivity for the oxidative product 2,5-furandicarboxylic acid (FDCA), and 100% Faradaic efficiency on a NiCo(OOH)
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Registered trials
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