Evidence map›Paper›PMID 40013335›Full record

ArticleAngewandte Chemie (International ed. in English)2025

Electronegative Strategic Positions in Covalent Organic Frameworks: Unlocking High-Efficiency Gold Recovery.

Zhongping Li, Wanyi Zhao, Changqing Li, Yawei Yin, Dongxue Wei, Yucheng Jin, Yongfeng Zhi, Jikuan Qiu, Yuwei Zhang, Jong-Beom Baek

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Zhongping LiSchool of Materials Science and Engineering, Jilin University, Changchun, 130012, P.R. China.
Wanyi ZhaoDepartment Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Jilin Normal University, Changchun, 130103, P.R. China.
Changqing LiDepartment of Energy and Chemical Engineering/Center for Dimension-Controllable Organic Frameworks, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 44919, Republic of Korea.
Yawei YinCollege of Chemical Engineering and Technology, Hainan University, Haikou, 570228, P.R. China.
Dongxue WeiDepartment Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Jilin Normal University, Changchun, 130103, P.R. China.
Yucheng JinDepartment of Energy and Chemical Engineering/Center for Dimension-Controllable Organic Frameworks, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 44919, Republic of Korea.
Yongfeng ZhiCollege of Chemical Engineering and Technology, Hainan University, Haikou, 570228, P.R. China.
Jikuan QiuDepartment of Energy and Chemical Engineering/Center for Dimension-Controllable Organic Frameworks, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 44919, Republic of Korea.
Yuwei ZhangDepartment Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Jilin Normal University, Changchun, 130103, P.R. China.
Jong-Beom BaekDepartment of Energy and Chemical Engineering/Center for Dimension-Controllable Organic Frameworks, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 44919, Republic of Korea.

Funding

Ministry of Science and ICT of KoreaNational Natural Science Foundation of Jilin province YDZJ202201ZYTS344National Research Foundation RS-2023-00221668National Research Foundation RS-2024-00435493National Research Foundation RS-2024-00466616
6 · The paper itself

Abstract

Gold (Au) concentrations accumulated from electronic waste (e-waste) and industrial leachates far surpass those found in natural ores, a highly valuable resource if efficient recovery methods can be developed. Despite advancements in covalent organic frameworks (COFs), achieving adsorbents with high selectivity, large capacity, and rapid adsorption kinetics remain challenging because of limitations in partial pore wall sites. Here, we present hexaazatriphenylene-based COFs (HATP-COFs) with an electronegative skeleton, specifically designed for selective Au recovery. The hexaazatriphenylene centers, imine linkages, and pyridine linkers within the COFs introduce electron-rich sites that extend across strategic positions-vertex, linkages, and linkers-thereby enhancing the overall structural integrity. These features facilitate efficient Au capture through electrostatic interactions, achieving an exceptional adsorption capacity exceeding 2366 mg g

Indexed as

Au captureCovalent organic frameworksElectronegative skeletonElectrostatic interactionHexaazatriphenylene

Identifiers

PMID40013335
PMCPMC12051782

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.