Evidence map›Paper›PMID 40005171›Full record

ArticleMolecules (Basel, Switzerland)2025

Synthesis, Photo-Physical Properties, and Electroluminescence Characteristics of Iridium Phosphorescent Materials Based on Different β-Diketonate Ancillary Ligands.

Qiaowen Chang, Ke Zhang, Caixian Yan, Liming Xie, Yuanqiuqiang Yi, Wenming Su, Weiping Liu

Abstract read
In one paragraph

Article in Molecules (Basel, Switzerland), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Qiaowen ChangState Key Laboratory of Precious Metal Functional Materials, Yunnan Precious Metals Laboratory, Kunming Institute of Precious Metals, Kunming 650106, China.ORCID 0000-0001-8724-4304
Ke ZhangState Key Laboratory of Precious Metal Functional Materials, Yunnan Precious Metals Laboratory, Kunming Institute of Precious Metals, Kunming 650106, China.
Caixian YanState Key Laboratory of Precious Metal Functional Materials, Yunnan Precious Metals Laboratory, Kunming Institute of Precious Metals, Kunming 650106, China.
Liming XiePrintable Electronics Research Center, Nano-Devices and Materials Division, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123, China.
Yuanqiuqiang YiPrintable Electronics Research Center, Nano-Devices and Materials Division, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123, China.
Wenming SuPrintable Electronics Research Center, Nano-Devices and Materials Division, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123, China.
Weiping LiuState Key Laboratory of Precious Metal Functional Materials, Yunnan Precious Metals Laboratory, Kunming Institute of Precious Metals, Kunming 650106, China.

Funding

China Postdoctoral Science Foundation 2020M681726National Natural Science Foundation of China 21861023Natural Science Foundation of Jiangsu Province BK20210125Natural Science Foundation of Yunnan Province 2019FA047Natural Science Foundation of Yunnan Province YPML-2022050230
6 · The paper itself

Abstract

Organic light-emitting diodes (OLEDs) based on phosphorescent materials are among the most promising technologies for displays and lightings. For red-emitting heteroleptic iridium complexes (HICs), vast and major research has been focused on the design and synthesis of cyclometalated ligands, while relatively little attention has been given to ancillary ligands which also play important roles in manipulating the optoelectronic and electroluminescent properties of HICs. Seven deep red-emitting HICs were designed and synthesized by systematically modifying the alkyl groups in β-diketone-type ancillary ligands. These HICs exhibited similar physical and optoelectronic properties, with OLED devices based on these materials achieving consistent emission peaks at 624 nm and CIE coordinates of (0.68, 0.32). Among the synthesized HICs, Ir(dmippiq)₂(dmeacac), featuring 3,7-dimethyl-4,6-nonanedione as the ancillary ligand, demonstrated the best OLED performance, achieving a champion external quantum efficiency (EQE) of 18.26%. This result highlights that engineering the alkyl groups in β-diketone ancillary ligands can significantly enhance device performance.

Indexed as

ancillary liganddeep-red emitteriridium (III) complexOLEDphosphorescent materials

Identifiers

PMID40005171
PMCPMC11858730

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.