ArticleMaterials (Basel, Switzerland)2025
Effect of Bayer Red Mud on the Mechanical Strength of Grouting Material.
Article in Materials (Basel, Switzerland), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The massive stockpiles of Bayer-process red mud (BRM) severely compromise soil integrity, necessitating the urgent development of efficient large-scale utilization strategies. BRM contains large amounts of calcium, silicon, and aluminum. Theoretically, water glass and flue gas desulfurization gypsum (FGD) can increase the active substances in BRM, making it a cementitious raw material capable of replacing cement. This study pioneers a novel activation strategy utilizing water glass-FGD synergism to amplify the BRM reactivity, enabling an increased dosage in construction materials through enhanced pozzolanic activity. They were blended into the cement at different ratios to prepare a grouting material (BF-C) for fissure sealing in mine rock strata. The hydration mechanism of BF-C was analyzed from a micro perspective by XRD, FTIR, ICP-OES, and SEM-EDS, and combined with the Ca/(Si + Al) ratio to reveal its hydration synergy. The results showed that the 3 d and 28 d strength of 70% BRM-FGD reached 8.94 MPa and 13.71 MPa, respectively. At this ratio, the hydration synergy of BF-C was the strongest. The addition of water glass and FGD can directly modulate the Ca/(Si + Al) ratio of the system to an optimal value of 0.94, which promotes the formation of early hydration products. C-S-H gel, calcite, and C(N)-A-S-H are the main hydration products of BF-C. C-S-H gels are encapsulated on cancrinite, and their three-dimensional network structures are dense. Meanwhile, C(N)-A-S-H crystals are interspersed between C-S-H gels, making the structure more stable. This achievement introduces an innovative method for the large-scale utilization of Bayer red mud, providing an effective solution in grouting technology using solid waste as raw material.
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