ArticleMaterials (Basel, Switzerland)2025
Influence of a Siloxane-Modified DOPO Derivative on the Properties of Polyurethane Cationomer Coatings.
Article in Materials (Basel, Switzerland), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Waterborne polyurethane cationomer coatings modified with 1,3-bis(3(3-(propoxy-2-ol-)-9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide)-3-propyloxy))tetramethyldisiloxane (TMDS-AGE-DOPA) containing phosphorus and silicon atoms were obtained. Their structures were confirmed by Fourier transform infrared (FTIR) spectroscopy. The effect of TMDS-AGE-DOPA on thermal properties, flame retardancy, and surface characteristics (gloss, contact angle, surface free energy), as well as performance properties (hardness, impact resistance), was investigated. A coupled TG-FTIR technique was employed for evolved gas analysis. Thermal stability decreased with the addition of the modifier, while the glass transition temperature increased from -19 to 25 °C. The modifier improved the flame retardancy of the material by shifting the peak temperature of the heat release rate (T
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