ArticleLight, science & applications2025
Accurately adjusted phenothiazine conformations: reversible conformation transformation at room temperature and self-recoverable stimuli-responsive phosphorescence.
Article in Light, science & applications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Recent advances in temperature and metastable-state effects on organic long-lived emission.Chemical science · 2026Review
- A new platform for achieving long-term air-stable long persistent luminescence in amorphous organic system.Light, science & applications · 2026Article
- Organic Cation Conformation-Modulated Dimensionality in Chiral Metal Halides for Enhancing Linear and Nonlinear Chiroptical Properties.Angewandte Chemie (International ed. in English) · 2026Article
- Red-light-excited dynamic near-infrared organic afterglow materials for in vivo bioimaging.Light, science & applications · 2026Article
- Phenothiazine-based TADF emitters with dual conformations for single-molecule white OLEDs.Chemical science · 2026Article
- Multistate density functional theory for local and charge-transfer tripdoublet states from triplet-free radical interactions.Advances in quantum chemistry · 2025Article
Corrections and comments
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Authors and funding
10 authors.
Funding
Abstract
Conformational flexibility is essential to the stimuli-responsive property of organic materials, but achieving the reversible molecular transformation is still challenging in functional materials for the high energy barriers and restriction by intermolecular interactions. Herein, through the incorporation of various steric hindrances into phenothiazine derivatives with different positions and quantities to tune the molecular conformations by adjustable repulsive forces, the folded angles gradually changed from 180° to 90° in 17 compounds. When the angle located at 112° with moderated steric effect, dynamic and reversible transformation of conformations under mechanical force has been achieved for the low energy barriers and mutually regulated molecular motions, resulting in both self-recoverable and stimuli-responsive phosphorescence properties for the first time. It opened up a new way to realize the self-recovery property of organic materials, which can facilitate the multi-functional property of smart materials with the opened avenue for other fields with inspiration.
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Registered trials
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