Evidence map›Paper›PMID 39995312›Full record

ArticleJournal of the American Chemical Society2025

Engineering Photoswitching Dynamics in 3D Photochromic Metal-Organic Frameworks through a Metal-Organic Polyhedron Design.

Eunji Jin, Volodymyr Bon, Shubhajit Das, A D Dinga Wonanke, Martin Etter, Martin A Karlsen, Ankita De, Nadine Bönisch, Thomas Heine, Stefan Kaskel

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Eunji JinChair of Inorganic Chemistry I, Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, Bergstraße 66, 01069 Dresden, Germany.ORCID 0000-0002-2103-6526
Volodymyr BonChair of Inorganic Chemistry I, Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, Bergstraße 66, 01069 Dresden, Germany.ORCID 0000-0002-9851-5031
Shubhajit DasChair of Theoretical Chemistry, Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, Bergstraße 66c, 01069 Dresden, Germany.ORCID 0000-0002-8027-6781
A D Dinga WonankeChair of Theoretical Chemistry, Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, Bergstraße 66c, 01069 Dresden, Germany.
Martin EtterP02.1 Beamline, PETRA III, Deutsches Elektronen-Synchrotron DESY, Notkestraße 85, 22607 Hamburg, Germany.
Martin A KarlsenP02.1 Beamline, PETRA III, Deutsches Elektronen-Synchrotron DESY, Notkestraße 85, 22607 Hamburg, Germany.ORCID 0000-0003-1262-8965
Ankita DeChair of Inorganic Chemistry I, Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, Bergstraße 66, 01069 Dresden, Germany.ORCID 0000-0003-4962-0510
Nadine BönischChair of Inorganic Chemistry I, Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, Bergstraße 66, 01069 Dresden, Germany.
Thomas HeineChair of Theoretical Chemistry, Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, Bergstraße 66c, 01069 Dresden, Germany.ORCID 0000-0003-2379-6251
Stefan KaskelChair of Inorganic Chemistry I, Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, Bergstraße 66, 01069 Dresden, Germany.ORCID 0000-0003-4572-0303

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Metal-organic polyhedra (MOPs) are versatile supramolecular building blocks for the design of highly porous frameworks by reticular assembly because of their diverse geometries, multiple degrees of freedom regarding functionalization, and accessible metal sites. Lipophilic functionalization is demonstrated to enable the rational assembly and crystallization with photoactive N-donor ligands in an aliphatic solvent to achieve multiaxially aligned photoresponsive diarylethene (DTE) moieties in 3D frameworks (DUT-210(M), M = Cu and Rh) featuring cooperative switchability. Combined experimental and theoretical investigations based on in situ PXRD, UV-vis spectroscopy, and density functional theory calculations demonstrate deliberate kinetic engineering of photoswitchability based on variations in metal-ligand bond strengths. The novel porous frameworks are an important step toward the knowledge-based development of photon-driven motors, actuators, and release systems.

Identifiers

PMID39995312
PMCPMC11912325

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.