ArticleNational science review2025
Modulating ion-dipole interactions in nonflammable phosphonate-based electrolyte for safe and stable sodium-ion pouch cells.
Article in National science review, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Synergistic Anion-Reinforced Solvation Chemistry and Cationic Electrostatic Shielding for Fast-Charging Sodium-Ion Full Batteries Over a Wide Temperature Range.Angewandte Chemie (International ed. in English) · 2026Article
- Fluorine-free acetonitrile-based electrolytes with anion-reinforced solvation chemistry for sustainable sodium-ion full batteries.Nature communications · 2026Article
- Dipolar interaction-mediated molecular anchoring electrolyte enables wide-temperature sodium-ion batteries with enhanced safety and durability.Nature communications · 2026Article
- Triple-Shell Hollow FeS/MoSAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
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Authors and funding
14 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Phosphonate-based electrolytes with the merits of low cost and intrinsic nonflammability are promising candidates to realize the safe operation of sodium-ion batteries. However, they generally suffer from poor interfacial chemistry because of the solvent-dominated solvation structure induced by the strong ion-dipole interactions between cations and phosphonate molecules. Herein, we report an electrolyte design strategy that selectively improves the competitive coordination of low-solvating-power molecules, achieving stable interfacial chemistry with a non-flammable, low-cost and fluorine-free electrolyte. By improving the ion-ion interaction between cation and anion, weakly coordinated molecules can enter the Na
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