Evidence map›Paper›PMID 39989376›Full record

ArticleAngewandte Chemie (International ed. in English)2025

Photogeneration and Visualization of a Surface-Stabilized Dinitrene.

Federico Frezza, Ana Sánchez-Grande, Sofia Canola, Christophe Nacci, Jiří Klívar, Pingo Mutombo, Qifan Chen, José María Gómez-Fernandez, Carlos Sánchez-Sánchez, Jan Berger and 6 more

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Review
  2. Review
  3. Photogeneration and Visualization of a Surface-Stabilized Dinitrene.Angewandte Chemie (International ed. in English) · 2025
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

16 authors.

Federico FrezzaInstitute of Physics, Czech Academy of Sciences, Cukrovarnická 10, 16200, Prague 6, Czech Republic.ORCID https://orcid.org/0000-0001-6511-3880
Ana Sánchez-GrandeInstitute of Physics, Czech Academy of Sciences, Cukrovarnická 10, 16200, Prague 6, Czech Republic.ORCID https://orcid.org/0000-0002-5499-0199
Sofia CanolaInstitute of Physics, Czech Academy of Sciences, Cukrovarnická 10, 16200, Prague 6, Czech Republic.ORCID https://orcid.org/0000-0002-8972-8203
Christophe NacciDepartment of Physical Chemistry, University of Graz, Heinrichstraße 28, 8010, Graz, Austria.ORCID https://orcid.org/0000-0002-6540-7202
Jiří KlívarInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo nám. 2, 16610, Prague 6, Czech Republic.ORCID https://orcid.org/0000-0001-8174-8720
Pingo MutomboInstitute of Physics, Czech Academy of Sciences, Cukrovarnická 10, 16200, Prague 6, Czech Republic.ORCID https://orcid.org/0000-0002-8175-7587
Qifan ChenInstitute of Physics, Czech Academy of Sciences, Cukrovarnická 10, 16200, Prague 6, Czech Republic.ORCID https://orcid.org/0009-0002-6276-3639
José María Gómez-FernandezInstituto de Ciencia de Materiales de Madrid, CSIC Cantoblanco, 28049, Madrid, Spain.ORCID https://orcid.org/0000-0002-6405-3879
Carlos Sánchez-SánchezInstituto de Ciencia de Materiales de Madrid, CSIC Cantoblanco, 28049, Madrid, Spain.ORCID https://orcid.org/0000-0001-8644-3766
Jan BergerInstitute of Physics, Czech Academy of Sciences, Cukrovarnická 10, 16200, Prague 6, Czech Republic.
Karl-Heinz ErnstInstitute of Physics, Czech Academy of Sciences, Cukrovarnická 10, 16200, Prague 6, Czech Republic.ORCID https://orcid.org/0000-0002-2077-4922
Irena G StaráInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo nám. 2, 16610, Prague 6, Czech Republic.ORCID https://orcid.org/0000-0002-5267-9604
José Ángel Martín-GagoInstituto de Ciencia de Materiales de Madrid, CSIC Cantoblanco, 28049, Madrid, Spain.ORCID https://orcid.org/0000-0003-2663-491X
Ivo StarýInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo nám. 2, 16610, Prague 6, Czech Republic.ORCID https://orcid.org/0000-0002-5468-3148
Leonhard GrillDepartment of Physical Chemistry, University of Graz, Heinrichstraße 28, 8010, Graz, Austria.ORCID https://orcid.org/0000-0002-9247-6502
Pavel JelínekInstitute of Physics, Czech Academy of Sciences, Cukrovarnická 10, 16200, Prague 6, Czech Republic.ORCID https://orcid.org/0000-0002-5645-8542

Funding

Austrian Science Fund I 5145-NAustrian Science Fund P 33527-NGrantová Agentura České Republiky 21-17194LMinisterstvo Školství, Mládeže a Tělovýchovy e-INFRA CZ LM2018140Ministerstvo Školství, Mládeže a Tělovýchovy LM2023051Ministerstvo Školství, Mládeže a Tělovýchovy MSCA Fellowship CZ FZU I-CZ.02.01.01/00/22_010/0002906
6 · The paper itself

Abstract

Nitrenes are known as key intermediates in various chemical reactions. Nitrene transfer reactions are particularly effective for synthesizing nitrogen-containing compounds, where metal catalysts play a crucial role in controlling nitrene reactivity and selectivity. In this study, we demonstrate the formation of a stable surface-supported dinitrene on Au(111) through UV irradiation of its diazide precursor, characterized by scanning probe techniques. The photoreaction mechanism is elucidated with wavelength-dependent experiments and time-dependent density functional theory calculations. Our findings present the first real-space visualization of a metal nitrene adsorbed on a surface, highlighting its potential in catalysis and surface functionalization.

Indexed as

azidemetal surfacenitrenephotochemistryscanning probe microscopy

Identifiers

PMID39989376
PMCPMC12070354

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.