Evidence map›Paper›PMID 39985245›Full record

ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2025

Achieving High-Performance Organic Long Persistent Luminescence Materials via Manipulation of Radical Cation Stability.

Hongxin Gao, Guangming Wang, Tengyue Wang, Zi Ye, Qianqian Yan, Qianhui Chong, Chin-Yiu Chan, Biaobing Wang, Kaka Zhang

Abstract read
In one paragraph

Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Hongxin GaoJiangsu Key Laboratory of Environmentally Friendly Polymeric Materials, School of Materials Science and Engineering, Jiangsu Collaborative Innovation Center of Photovoltaic Science and Engineering, Changzhou University, 21 Gehuzhong Road, Changzhou, 213100, P. R. China.
Guangming WangState Key Laboratory of Organometallic Chemistry, Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, University of Chinese Academy of Sciences, 345 Lingling Road, Shanghai, 200032, P. R. China.
Tengyue WangState Key Laboratory of Organometallic Chemistry, Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, University of Chinese Academy of Sciences, 345 Lingling Road, Shanghai, 200032, P. R. China.
Zi YeState Key Laboratory of Organometallic Chemistry, Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, University of Chinese Academy of Sciences, 345 Lingling Road, Shanghai, 200032, P. R. China.
Qianqian YanState Key Laboratory of Organometallic Chemistry, Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, University of Chinese Academy of Sciences, 345 Lingling Road, Shanghai, 200032, P. R. China.
Qianhui ChongJiangsu Key Laboratory of Environmentally Friendly Polymeric Materials, School of Materials Science and Engineering, Jiangsu Collaborative Innovation Center of Photovoltaic Science and Engineering, Changzhou University, 21 Gehuzhong Road, Changzhou, 213100, P. R. China.
Chin-Yiu ChanDepartment of Materials Science and Engineering, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong SAR, 999077, China.
Biaobing WangJiangsu Key Laboratory of Environmentally Friendly Polymeric Materials, School of Materials Science and Engineering, Jiangsu Collaborative Innovation Center of Photovoltaic Science and Engineering, Changzhou University, 21 Gehuzhong Road, Changzhou, 213100, P. R. China.
Kaka ZhangState Key Laboratory of Organometallic Chemistry, Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, University of Chinese Academy of Sciences, 345 Lingling Road, Shanghai, 200032, P. R. China.ORCID https://orcid.org/0000-0002-8176-6205

Funding

Hundred Talents Program from Shanghai Institute of Organic Chemistry Y121078National Natural Science Foundation of China 22175194National Natural Science Foundation of China 22475228Natural Science Foundation of Ningbo Municipality 2023J243Pioneer Hundred Talents Program of Chinese Academy of Sciences E320021Strategic Priority Research Program of the Chinese Academy of Sciences XDB0610000
6 · The paper itself

Abstract

Organic long persistent luminescence (OLPL) materials, with their hour-long afterglow, hold great promise across numerous applications, yet their performance lags behind that of inorganic counterparts. A deeper understanding of the underlying photophysical mechanisms, particularly the effective control of radical intermediates, is essential for developing high-performance OLPL materials; while systematic studies on the intrinsic stability of radical intermediates and their impact on OLPL performance remain scarce. Here biphenyl groups is introduced into a luminophore-matrix-donor three-component OLPL system. By varying substituents at the ortho-position of the biphenyl groups, the stability of radical cations is systematically modulated, and their influence on OLPL properties is investigated. Combined experimental results and theoretical calculations reveal that increased flexibility of the biphenyl bond and adjustable conformations lead to higher stability of radical cations, thereby significantly enhancing OLPL performance. Based on this understanding, a luminophore with two biphenyl groups is designed to successfully achieve remarkable afterglow brightness close to inorganic Sr

Indexed as

difluoroboron β‐diketonateorganic aftergloworganic long persistent luminescenceradical cationroom‐temperature phosphorescence

Identifiers

PMID39985245
PMCPMC12005741

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.