ArticleNature communications2025
Facilitating alkaline hydrogen evolution kinetics via interfacial modulation of hydrogen-bond networks by porous amine cages.
Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
What it found
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The trial behind it
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Who cites it
14 citing papers in PubMed.
- Interfacial hydrogen transfer for heterogeneous catalysis.Nature reviews. Chemistry · 2026Review
- Paracrystalline IrCoONature communications · 2026Article
- Dual Regulation of Molecular Orbital and Interfacial Water on Nickel Phthalocyanine for Highly Selective HAngewandte Chemie (International ed. in English) · 2026Article
- Interfacial Confinement-Programmed Hydrogen Spillover on Ag/CoNiS Boosts Nitrate-to-Ammonia Electrosynthesis.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- In Situ Probing of Electrochemical Hydrogen Evolution Reaction Intermediates: From Single-Crystal Models to Nano-Catalysts.Nano-micro letters · 2026Review
- Confining ultrasmall Au nanoclusters in an ionic Ir(iii)-based cage for selective photoreduction.Chemical science · 2026Article
- Scalable Ni‑driven synthesis of Pt single‑site catalysts for hydrogen evolution.Nature communications · 2026Article
- Conjugation Lock-In Reinforced Sulfur-Heteropolycyclic Covalent Organic Frameworks with Asymmetric Electron Distribution for Photocatalytic Aerobic Oxidation Reactions.Journal of the American Chemical Society · 2026Article
- Tailoring Intermediate Adsorption Through d-band Mismatch Strategy of Heterojunction to Achieve Industrial Overall Water Splitting.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Surface coating accelerates cathode development for next-generation anion exchange membrane water electrolysis.Innovation (Cambridge (Mass.)) · 2026Review
- P-N heterojunction-enhanced structural stability of tungsten disulfide nanosheets for highly efficient, stable alkaline water electrolysis.RSC advances · 2025Article
- Ce Single Atom-Engineered Amorphous/Crystalline Nanosheets for Enhanced Alkaline Water Electrolysis.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Descriptor-Guided Design of Mo-Doped FeCoNiCu High-Entropy Alloy Electrocatalysts Surpassing Pt for Alkaline Hydrogen Evolution.ACS applied materials & interfaces · 2025Article
- Space-Confined Electrocatalysis for Water Splitting: Synthesis, Performances, and Reaction Mechanism of Nanomaterials Toward High-Performance Catalysis.Angewandte Chemie (International ed. in English) · 2025Review
Corrections and comments
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Authors and funding
8 authors.
Funding
Abstract
The electrode-electrolyte interface is pivotal in the electrochemical kinetics. However, modulating the electrochemical interface at the atomic or molecular level is challenging due to the lack of efficient interfacial regulators. Here, we employ a porous amine cage as an interfacial modifier to Pt cluster in a confining configuration, largely enhancing alkaline HER kinetics by facilitating charge transfer. In situ electrochemical surface-enhanced Raman spectra, in combination with the ab initio molecular dynamics simulation, elucidates that the interaction between water and the -NH- moiety of cage frame softens the H-bonds net of interfacial water, making it more flexible for charge transfer. Moreover, our investigation pinpointed that the -NH- moiety acted as a pump for charge transfer by Grotthuss mechanism, lowering the kinetic barrier for hydrogen adsorption. Our findings highlight the strategy of establishing a soft-confining interfacial modifier by porous cage, offering opportunities to optimize electrochemical interfaces and promote reaction kinetics in a targeted way.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.