Evidence map›Paper›PMID 39981026›Full record

ArticleNational science review2025

Nucleophilic cleavage of C-F bonds by Brønsted base for rapid synthesis of fluorophosphate materials.

Qingfeng Fu, Zihao Chang, Peng Gao, Wang Zhou, Hongliang Dong, Peifeng Huang, Aiping Hu, Changling Fan, Peitao Xiao, Yufang Chen and 1 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in National science review, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Chalcogen-Directed Dual-Heterointerfaced BiSmall (Weinheim an der Bergstrasse, Germany) · 2026
    Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Qingfeng FuCollege of Materials Science and Engineering, Hunan Joint International Laboratory of Advanced Materials and Technology for Clean Energy, Hunan Province Key Laboratory for Advanced Carbon Materials and Applied Technology, Hunan University, Changsha 410082, China.ORCID https://orcid.org/0000-0001-7809-2214
Zihao ChangState Key Laboratory of Advanced Design and Manufacturing for Vehicle Body, Hunan University, Changsha 410082, China.
Peng GaoCollege of Materials Science and Engineering, Hunan Joint International Laboratory of Advanced Materials and Technology for Clean Energy, Hunan Province Key Laboratory for Advanced Carbon Materials and Applied Technology, Hunan University, Changsha 410082, China.
Wang ZhouCollege of Materials Science and Engineering, Hunan Joint International Laboratory of Advanced Materials and Technology for Clean Energy, Hunan Province Key Laboratory for Advanced Carbon Materials and Applied Technology, Hunan University, Changsha 410082, China.
Hongliang DongCenter for High Pressure Science and Technology Advanced Research, Shanghai 201203, China.
Peifeng HuangState Key Laboratory of Advanced Design and Manufacturing for Vehicle Body, Hunan University, Changsha 410082, China.
Aiping HuCollege of Materials Science and Engineering, Hunan Joint International Laboratory of Advanced Materials and Technology for Clean Energy, Hunan Province Key Laboratory for Advanced Carbon Materials and Applied Technology, Hunan University, Changsha 410082, China.
Changling FanCollege of Materials Science and Engineering, Hunan Joint International Laboratory of Advanced Materials and Technology for Clean Energy, Hunan Province Key Laboratory for Advanced Carbon Materials and Applied Technology, Hunan University, Changsha 410082, China.
Peitao XiaoCollege of Aerospace Science and Engineering, National University of Defense Technology, Changsha 410073, China.
Yufang ChenCollege of Aerospace Science and Engineering, National University of Defense Technology, Changsha 410073, China.
Jilei LiuCollege of Materials Science and Engineering, Hunan Joint International Laboratory of Advanced Materials and Technology for Clean Energy, Hunan Province Key Laboratory for Advanced Carbon Materials and Applied Technology, Hunan University, Changsha 410082, China.ORCID https://orcid.org/0000-0003-0571-323X

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Fluorochemicals are a rapidly expanding class of materials used in a variety of fields including pharmaceuticals, metallurgy, agrochemicals, refrigerants, and in particular, alkali metal ion batteries. However, achieving one-step synthesis of pure fluorophosphate compounds in a well-controlled manner remains a formidable challenge due to the volatilization of fluorine during the heat treatment process. One feasible method is to cleave the C-F bond in polytetrafluoroethylene (PTFE) during synthesis to create a fluorine-rich atmosphere and strongly reducing environment. However, the inert nature of the C-F bond in PTFE presents a significant obstacle, as it is the strongest single bond in organic compounds. To address this predicament, we propose a fluorine-compensating strategy that involves cleavage of the C-F bonds by nucleophilic S

Indexed as

C–F bondfluorophosphate compoundspolytetrafluoroethylenepotassium-ion battery

Identifiers

PMID39981026
PMCPMC11841365

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.