ArticleNature chemistry2025
Moiré two-dimensional covalent organic framework superlattices.
Article in Nature chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed.
- Programming stacking order in conducting van der Waals metal-organic frameworks through ligand aggregation.Nature chemistry · 2026Article
- Imaging Multistep s‑Triazine Oligomerization via Cobalt-Assisted Deamination and Selective C-C Coupling.Precision chemistry · 2026Article
- Mechanistic Insights into Layered Growth of Imine-Linked Bilayer 2D Covalent Organic Frameworks.Journal of the American Chemical Society · 2026Article
- Electric-Field-Mediated Molecular Scalpel for Programmable Cleavage and Reconfiguration of Monolayer Covalent Organic Frameworks.Journal of the American Chemical Society · 2026Article
- Synthesis, characterisation, computational study, amelioration of ruthenium kesar nanoparticle, antioxidant and glycolytic enzyme activity alterations in cirrhotic liver extract.Scientific reports · 2026Article
- Stacking Order-Mediated Spin-State Modulation in Iron Phthalocyanine Covalent Organic Frameworks Enables Efficient Oxygen Reduction Reaction.ACS applied materials & interfaces · 2026Article
- "Tear-And-Stack" Twisted SrTiOAdvanced materials (Deerfield Beach, Fla.) · 2026Article
- Flexible High-Aspect-Ratio COF Nanofibers: Defect-Engineered Synthesis, Superelastic Aerogels, and Uranium Extraction Applications.Nano-micro letters · 2026Article
- Mechanically interlocked monolayer and bilayer two-dimensional polymers with high elastic modulus.Nature synthesis · 2026Article
- Radial growth of twist-stacked covalent organic framework nanofibers.Nature communications · 2025Article
- Why covalent organic frameworks grow twisted on graphite.Nature communications · 2025Article
- 1D axial heterostructure of hydrogen-bonded framework and metal-organic framework by metalation reaction.Nature communications · 2025Article
- Article
- Strain release through hydrogen bond-mediated layer twisting.Science advances · 2025Article
- Metallocene-anchor inducing oriented MOF membrane for helium separation.Nature communications · 2025Article
Corrections and comments
- Erratum issued
Authors and funding
19 authors.
Funding
Abstract
The on-surface synthesis of two-dimensional (2D) polymers from monomers represents a useful strategy for designing lattice, orbital and spin symmetries. Like other 2D materials, the ordered stacking of 2D polymers into bilayers may allow developing unique optoelectronic, charge transport and magnetic properties not found in the individual layers. However, controlling layer stacking of 2D polymers remains challenging. Here we describe a method for synthesizing 2D polymer bilayers or bilayer 2D covalent organic frameworks at the liquid-substrate interface through the direct condensation of monomers. More importantly, we also show how factors such as monomer structure and solvent mixture influence the bilayer stacking modes and how, under certain conditions, large-area moiré superlattices emerge from the twisted bilayer stacking. This finding offers new opportunities for the design of bilayer stacked framework materials with tunable electronic and structural properties.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.