ArticleJournal of the American Chemical Society2025
Manipulating a Thermosalient Crystal Using Selective Deuteration.
Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
1 citing paper in PubMed.
- Crystals as Rockets: Modulation of the Salient Temperature in Cocrystals by Solvent Mixture Composition.Angewandte Chemie (International ed. in English) · 2026Article
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The thermosalient transformation in nickel(II) bis(diisopropyl)dithiocarbamate has been investigated using selective deuteration. The deuterated crystals undergo a reversible displacive phase transition that is ∼4 K higher in temperature compared to the protonated analogue. Neutron, synchrotron, density-functional theory, and calorimetric techniques were utilized to demonstrate the substantial effect of deuterium. All techniques demonstrated the equivalence of the mechanism on an atomic scale between the protonated and deuterated complexes. The data collected in this study reveal details of the changes of atomic motion that underpin the thermosalience inherent in this system. Deuterium decreased the frequency of atomic vibrations thus increasing the temperature of the observed transformation. This study represents a key advancement in the field of thermosalient molecular systems and provides insights into the control and manipulation of thermosalient materials.
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Registered trials
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