Evidence map›Paper›PMID 39974700›Full record

ArticleChem & bio engineering2024

Deciphering Metal-Organic Framework Synthesis from Hydroxy Double Salts: In-Situ Insights via Synchrotron X-ray Diffraction and Absorption Spectroscopy.

Ming Zhang, Xinyu Luo, Yubin Hu, Yuanhao Shen, Yixin Chen, Shuchang Yuan, Hao Wang, Xueqing Xing, Junjie Zhao

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chem & bio engineering, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Ming ZhangState Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, 866 Yuhangtang Rd, Hangzhou, Zhejiang 310058, P. R. China.
Xinyu LuoState Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, 866 Yuhangtang Rd, Hangzhou, Zhejiang 310058, P. R. China.
Yubin HuState Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, 866 Yuhangtang Rd, Hangzhou, Zhejiang 310058, P. R. China.
Yuanhao ShenState Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, 866 Yuhangtang Rd, Hangzhou, Zhejiang 310058, P. R. China.
Yixin ChenState Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, 866 Yuhangtang Rd, Hangzhou, Zhejiang 310058, P. R. China.
Shuchang YuanState Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, 866 Yuhangtang Rd, Hangzhou, Zhejiang 310058, P. R. China.
Hao WangBeijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, 19 Yuquan Road, Beijing 100049, P. R. China.
Xueqing XingBeijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, 19 Yuquan Road, Beijing 100049, P. R. China.ORCID https://orcid.org/0000-0002-1052-6319
Junjie ZhaoState Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, 866 Yuhangtang Rd, Hangzhou, Zhejiang 310058, P. R. China.ORCID https://orcid.org/0000-0001-6205-9671

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Developing rapid room-temperature synthesis is key to sustainable manufacturing of metal-organic frameworks (MOFs). Using layered compounds such as hydroxy double salts (HDSs) as precursors significantly promotes the reaction kinetics and lowers the required synthesis temperature. However, limited understanding of the reaction mechanism impedes the further exploration of new routes for MOF synthesis. Here, we report for the first time the use of combined in-situ synchrotron X-ray diffraction and X-ray absorption spectroscopy to monitor the dynamic processes to form MOFs in solution. The conversion from a (Zn,Co) HDS to a mixed-metal zeolitic imidazolate framework-8 (mmZIF-8) was chosen as our model reaction. Time-resolved diffraction patterns exclude the presence of intercalated HDS structures with altered

Identifiers

PMID39974700
PMCPMC11835274

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.