Hydration/Dehydration Induced Reversible Transformation between a Porous Hydrogen-Bonded Organic Framework and a Nonporous Molecular Crystal for Highly Efficient Gas Dehydration.

Yao Wang, Xiyu Song, Guanglai Mo, Xiangyu Gao, Enyu Wu, Bin Li, Yunbo Bi, Peng Li

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Article in Chem & bio engineering, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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5 · Who and what money

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8 authors.

Yao WangShanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai 200438, P. R. China.ORCID https://orcid.org/0000-0002-0378-1805

Xiyu SongShanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai 200438, P. R. China.ORCID https://orcid.org/0000-0002-0208-8259

Guanglai MoShanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai 200438, P. R. China.

Xiangyu GaoShanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai 200438, P. R. China.

Enyu WuState Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hang-zhou 310027 China.

Bin LiState Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hang-zhou 310027 China.ORCID https://orcid.org/0000-0002-7774-5452

Yunbo BiShanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai 200438, P. R. China.

Peng LiShanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai 200438, P. R. China.ORCID https://orcid.org/0000-0002-4273-4577

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Gas dehydration is a critical process in gas transportation and chemical reactions, yet traditional drying agents require an energy-intensive dehydration and regeneration step. Here, we present a nonporous molecular crystal called Melem that can be synthesized and scaled up through solid-state synthesis methods. Melem exhibits exceptional water selectivity in gas dehydration and can be reactivated under moderate conditions. According to the single-crystal structure and powder X-ray diffraction studies, a reversible structural transformation between Melem and its hydrated form, Melem-H

Identifiers

PMID39974469

DOI10.1021/cbe.3c00114

PMCPMC11835148

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.