ArticleOrganic letters2025
Merging Photoexcited Nitroarenes with Lewis Acid Catalysis for the Anti-Markovnikov Oxidation of Alkenes.
Article in Organic letters, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- One-Step Photoreduction of Nitroarenes to Nitrosoarenes.Organic letters · 2026Article
- Harnessing nitroarenes as nitrogen and oxygen sources for general oxo-aminomethylation of alkenes.Nature communications · 2025Article
- Radical Formation by Direct Single Electron Transfer between Nitrobenzene and Anionic Organo Bases.ACS omega · 2025Article
- Photoexcited nitroarene-enabled carbon chain-elongated oxidation of alkenes via tandem oxidative cleavage and dipolar cycloaddition.Nature communications · 2025Article
- Merging Photoexcited Nitroarenes with Lewis Acid Catalysis for the Anti-Markovnikov Oxidation of Alkenes.Organic letters · 2025Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
Herein we describe the oxidation of alkenes to carbonyls and acetonides via the interplay of photoexcited nitroarenes and Lewis acid catalysis. A wide range of alkenes were oxidized to aldehyde and ketone products with anti-Markovnikov selectivity and to acetonides when acetone was employed as a co-solvent. Mechanistic studies support that Lewis acid coordination to the 1,3,2-dioxazolidine intermediate results in a 1,2-shift to generate carbonyl derivatives and a nucleophilic substitution pathway for the formation of acetonides.
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