Evidence map›Paper›PMID 39972930›Full record

ArticleAdvanced materials (Deerfield Beach, Fla.)2025

Unravelling the Atomic Structure of a Metal-Covalent Organic Framework Assembled from Ruthenium Metalloligands.

Seán Hennessey, Roberto González-Gómez, Nicolás Arisnabarreta, Anna Ciotti, Jing Hou, Nadezda V Tarakina, Andrey Bezrukov, Kunal S Mali, Michael Zaworotko, Steven De Feyter and 2 more

Abstract read
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In one paragraph

Article in Advanced materials (Deerfield Beach, Fla.), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors.

Seán HennesseySchool of Biological and Chemical Sciences, Energy Research Centre, Ryan Institute, University of Galway, University Road, Galway, H91 TK33, Ireland.ORCID https://orcid.org/0000-0002-5406-518X
Roberto González-GómezSchool of Biological and Chemical Sciences, Energy Research Centre, Ryan Institute, University of Galway, University Road, Galway, H91 TK33, Ireland.ORCID https://orcid.org/0000-0003-4200-2541
Nicolás ArisnabarretaDivision of Molecular Imaging, Photonics, Department of Chemistry, KU Leuven, Celestijnenlaan 200F, Leuven, 3001, Belgium.ORCID https://orcid.org/0000-0002-9546-1250
Anna CiottiSchool of Chemistry, CRANN and AMBER Research Centres, Trinity College Dublin, College Green, Dublin, D02 PN40, Ireland.
Jing HouDepartment of Colloid Chemistry, Max Planck Institute of Colloids and Interfaces, Research Campus Golm, Am Mühlenberg 1, 14476, Potsdam, Germany.
Nadezda V TarakinaDepartment of Colloid Chemistry, Max Planck Institute of Colloids and Interfaces, Research Campus Golm, Am Mühlenberg 1, 14476, Potsdam, Germany.ORCID https://orcid.org/0000-0002-2365-861X
Andrey BezrukovBernal Institute, University of Limerick, Limerick, V94 T9PX, Ireland.ORCID https://orcid.org/0000-0002-0525-3547
Kunal S MaliDivision of Molecular Imaging, Photonics, Department of Chemistry, KU Leuven, Celestijnenlaan 200F, Leuven, 3001, Belgium.ORCID https://orcid.org/0000-0002-9938-6446
Michael ZaworotkoBernal Institute, University of Limerick, Limerick, V94 T9PX, Ireland.ORCID https://orcid.org/0000-0002-1360-540X
Steven De FeyterDivision of Molecular Imaging, Photonics, Department of Chemistry, KU Leuven, Celestijnenlaan 200F, Leuven, 3001, Belgium.ORCID https://orcid.org/0000-0002-0909-9292
Max García-MelchorCenter for Cooperative Research on Alternative Energy (CIC EnergiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, Albert Einstein 48, Vitoria- Gasteiz, 01510, Spain.ORCID https://orcid.org/0000-0003-1348-4692
Pau FarràsSchool of Biological and Chemical Sciences, Energy Research Centre, Ryan Institute, University of Galway, University Road, Galway, H91 TK33, Ireland.ORCID https://orcid.org/0000-0003-3859-2868

Funding

FWO 12ZS623NH2020 Excellent Science 101022202HORIZON EUROPE Framework Programme 101046231KU Leuven (Internal Funds) C14/23/090Research Foundation - Flanders (FWO) project G0A4120NResearch Foundation - Flanders (FWO) project G0K9822NScience Foundation Ireland 12/RC/2278_P2
6 · The paper itself

Abstract

Covalent and metal-organic frameworks (COFs and MOFs) have shown great promise in light-driven processes mainly due to their ligand-to-metal charge-separation properties, as well as having access to a diverse range of photoactive metalloligands and organic linkers. However, both frameworks present individual drawbacks that can potentially be avoided by combining both systems (metal and covalent) to produce metal-covalent organic frameworks (MCOFs), exhibiting the advantages of both material types. Yet, due to their poor crystallinity, the understanding of the structure-properties relation of MCOFs remains unclear. Herein, we report photoactive linkers in the form of a [Ru(tpy)

Indexed as

2D frameworksDFT calculationsmetal‐covalent organic frameworkmetalloligandsphotoactive materials

Identifiers

PMID39972930
PMCPMC11962698

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.