ReviewAngewandte Chemie (International ed. in English)2025
Towards Surface-Enhanced Homogeneous Catalysis: Tailoring the Enrichment of Metal Complexes at Ionic Liquid Surfaces.
Review in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
4 citing papers in PubMed.
- Interfacial Enrichment and Demetallation of a Zinc Porphyrin in the Ionic Liquid [CChemphyschem : a European journal of chemical physics and physical chemistry · 2026Article
- Click Heterogenization of Phosphines Furnishes Recyclable Hydroformylation Catalysts that Reproduce Homogeneous Performance.Journal of the American Chemical Society · 2025Article
- Influence of ionic liquid composition on surface enrichment of fluorine-free Ru complexes.RSC advances · 2025Article
- Towards Surface-Enhanced Homogeneous Catalysis: Tailoring the Enrichment of Metal Complexes at Ionic Liquid Surfaces.Angewandte Chemie (International ed. in English) · 2025Review
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
8 authors.
Funding
Abstract
When talking about homogeneous catalyst systems, it has long been assumed that the system at hand consists of a transition metal complex in solution with the liquid interface representing the composition of the bulk solution. Now, in light of considerable developments in the study of metal complexes dissolved in ionic liquids with their negligible vapor pressures, more detailed studies of the composition at the liquid/gas interface became possible. These investigations revealed pronounced surface enrichment and segregation effects of high relevance for practical applications. This article reviews recent advancements in tailoring the interfacial composition of ionic liquid-based catalytic systems. A particular focus is dedicated to surface enrichment phenomena, and a variety of parameters are presented for deliberate control of the local concentration of the complexes at the surface, that is, the nature of the ligands, the bulk concentration, the temperature, and the nature of the IL solvent. As experimental methods, angle-resolved X-ray photoelectron spectroscopy (ARXPS) and vacuum-based pendant-drop surface tension measurements were applied. The reviewed results are intended to provide the basis for the advancement of catalytic systems with high surface areas, such as in supported ionic liquid phase (SILP) catalysis, where the interface design is directly interconnected with catalytic performance.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.