Evidence map›Paper›PMID 39961060›Full record

ArticleSmall (Weinheim an der Bergstrasse, Germany)2025

Substrate Stabilized Charge Transfer Scheme In Coverage Controlled 2D Metal Organic Frameworks.

Simone Mearini, Dominik Brandstetter, Yan Yan Grisan Qiu, Daniel Baranowski, Iulia Cojocariu, Matteo Jugovac, Pierluigi Gargiani, Manuel Valvidares, Luca Schio, Luca Floreano and 4 more

Abstract read
In one paragraph

Article in Small (Weinheim an der Bergstrasse, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed.

  1. Article
  2. Zero-Valent Nickel Stabilized in Surface-Supported Metal-Organic Chains.Angewandte Chemie (International ed. in English) · 2026
    Article
  3. Article
  4. Article
  5. Revealing the Character of Coordination Bonding in 2D Metal-Organic Frameworks.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025
    Article
  6. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

14 authors.

Simone MeariniPeter Grünberg Institute (PGI-6), Jülich Research Centre, 52428, Jülich, Germany.ORCID https://orcid.org/0009-0009-9531-1533
Dominik BrandstetterInstitute of Physics, University of Graz, Graz, 8010, Austria.ORCID https://orcid.org/0000-0002-0434-1289
Yan Yan Grisan QiuPeter Grünberg Institute (PGI-6), Jülich Research Centre, 52428, Jülich, Germany.ORCID https://orcid.org/0009-0007-8629-9582
Daniel BaranowskiPeter Grünberg Institute (PGI-6), Jülich Research Centre, 52428, Jülich, Germany.ORCID https://orcid.org/0000-0002-2533-3093
Iulia CojocariuPhysics Department, University of Trieste, Trieste, 34127, Italy.ORCID https://orcid.org/0000-0002-6408-3541
Matteo JugovacPhysics Department, University of Trieste, Trieste, 34127, Italy.ORCID https://orcid.org/0000-0001-9525-3980
Pierluigi GargianiALBA Synchrotron Light Source, Barcelona, 08290, Spain.ORCID https://orcid.org/0000-0002-6649-0538
Manuel ValvidaresALBA Synchrotron Light Source, Barcelona, 08290, Spain.ORCID https://orcid.org/0000-0003-4895-8114
Luca SchioCNR - Istituto Officina dei Materiali (IOM), TASC Laboratory, Basovizza, Trieste, 34149, Italy.ORCID https://orcid.org/0000-0001-8101-4022
Luca FloreanoCNR - Istituto Officina dei Materiali (IOM), TASC Laboratory, Basovizza, Trieste, 34149, Italy.ORCID https://orcid.org/0000-0002-3654-3408
Andreas WindischbacherInstitute of Physics, University of Graz, Graz, 8010, Austria.ORCID https://orcid.org/0000-0002-8353-6681
Peter PuschnigInstitute of Physics, University of Graz, Graz, 8010, Austria.ORCID https://orcid.org/0000-0002-8057-7795
Vitaliy FeyerPeter Grünberg Institute (PGI-6), Jülich Research Centre, 52428, Jülich, Germany.ORCID https://orcid.org/0000-0002-7104-5420
Claus Michael SchneiderPeter Grünberg Institute (PGI-6), Jülich Research Centre, 52428, Jülich, Germany.ORCID https://orcid.org/0000-0002-3920-6255

Funding

Austrian Science Fund (FWF) PAT1379523Deutsche Forschungsgemeinschaft 513136560European Research Council 101071259Horizon 2020 101007417Vienna Scientific Cluster
6 · The paper itself

Abstract

Recently, 2D metal-organic frameworks (2D MOFs), characterized by complex charge transfer mechanisms, have emerged as a promising class of networks in the development of advanced materials with tailored electronic and magnetic properties. Following the successful synthesis of a 2D MOF formed by nickel (Ni) linkers and 7,7,8,8-tetracyanoquinodimethane (TCNQ) ligands, this work investigates how the Ni-to-ligand ratio influences the electronic charge redistribution in an Ag(100)-supported 2D MOF. The interplay between linker-ligand and substrate-MOF charge transfer processes leads to a stable equilibrium, resulting in a robust electronic structure that remains independent of stoichiometric ratios. This stability is primarily based on the electron transfer from the metal substrate, which compensates for charge imbalances introduced by the metal-organic coordination across different MOF configurations. Despite minor changes observed in the magnetic response of the Ni centers, these findings emphasize the robustness of the electronic structure, which remains largely unaffected by structural variations, highlighting the potential of these 2D MOFs for advanced applications in electronics and spintronics.

Indexed as

2D materialscharge transfermolecular ligandssingle‐layer metal‐organic frameworkstransition metals

Identifiers

PMID39961060
PMCPMC11947512

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.