ArticleSmall (Weinheim an der Bergstrasse, Germany)2025
Triphenylamine-Based Porous Organic Polymers with High Porosity: their High Carbon-Dioxide Adsorption and Proton-Conductivity Emergence.
Article in Small (Weinheim an der Bergstrasse, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Synthesis of High-Purity Porous Organic Polymers and Exploration of Their Inherent Functionality.ACS applied materials & interfaces · 2026Review
- Molecular Design Strategy of π-Conjugated Polymers for Efficient Visible-Light-Driven Photoelectrocatalytic OChemSusChem · 2026Article
- Triphenylamine-Based Porous Organic Polymers with High Porosity: their High Carbon-Dioxide Adsorption and Proton-Conductivity Emergence.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
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4 authors.
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Abstract
Amorphous porous organic polymers (POPs) feature high specific surface area and chemical and thermal stability; therefore, they are applied in various fields. It is previously reported that chemical polymerization using iodine as an oxidant enables the synthesis of amorphous POPs without impurities. In this study, an iodine-based chemical polymerization method is employed to maximize the specific surface area of polytriphenylamine, a typical amorphous POP. Furthermore, 1,3,5-tris[4-(diphenylamino)phenyl]benzene, a monomer with three triphenylamine moieties connected by a benzene core, is used to increase the number of reaction points and construct a rigid structure. The resulting poly[1,3,5-tris[4-(diphenylamino)phenyl]benzene] (pTTPA) exhibited a high specific surface area. Using 200 equivalents of iodine resulted in a pTTPA with the largest Brunauer-Emmett-Teller (BET) specific surface area (2134.6 m
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