ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2025
4D Assembly of Time-dependent Lanthanide Supramolecular Multicolor Phosphorescence for Encryption and Visual Sensing.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Time-evolving self-assembly of a single-component fluorophore enables dynamic emission for temporal information encryption and self-erasing writing.Chemical science · 2026Article
- Multi-Dimensional Acoustic Cascaded Holographic Encryption with Instantaneous Visual Decryption via Particle Manipulation.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- A reflection on enzyme-coupled supramolecular sensing: overcoming selectivity barriers with macrocyclic reporter pairs.Chemical science · 2025Article
- Multicolor Luminescent Supramolecular Bidirectional Shuttles Driven by Light.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- 4D Assembly of Time-dependent Lanthanide Supramolecular Multicolor Phosphorescence for Encryption and Visual Sensing.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
Corrections and comments
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Authors and funding
8 authors.
Funding
Abstract
Supramolecular dynamic room temperature phosphorescence (RTP) is the focus of current research because of its wide application in biological imaging and information anti-counterfeiting. Herein, a time-dependent supramolecular lanthanide phosphorescent 4D assembly material with multicolor luminescence including white, which is composed of 4-(4-bromophenyl)-pyridine salt derivative (G), inorganic clay (LP)/Eu complex and pyridine dicarboxylic acid (DPA) is reported. Compared with the self-assembled nanoparticle G, the lamellar assembly G/LP showed the double emission of fluorescence at 380 nm and phosphorescence at 516 nm over time. Within 60 min, the phosphorescence lifetime and the quantum yield increases from none to 7.4 ms and 27.53% respectively, achieving the time-dependent phosphorescence emission, due to the limitation of progressive stacking of LP electrostatically driven "domino effect." Furthermore, the 4D assembly of DPA and G/LP/Eu leads to a time-resolved multicolor emission from colorless to purple to white, which is successfully applied to information multi-level logic anti-counterfeiting and efficiently antibiotic selective sensor.
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