ArticleJournal of the American Chemical Society2025
Precise Carboxylic Acid-Functionalized Polyesters in Reprocessable Vitrimers.
Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
5 citing papers in PubMed.
- Precise Structural Design for Chemically Recyclable Polymers.Precision chemistry · 2026Review
- Aqueous-Phase Polycondensation of Hydroxy Fatty Acids via a Whole-Cell CoA Activation-Acyltransferase Cascade.JACS Au · 2026Article
- Rational Design of Ionomer Microstructures for Thermally Reprocessable Materials with Creep Resistance and Recoverability.JACS Au · 2025Article
- Recoverable Fluorination Accelerates Ring-Opening Copolymerisation and Enables Post-Polymerisation-Modification of Polyesters.Angewandte Chemie (International ed. in English) · 2025Article
- A review on the formulation and performance of epoxidized vegetable oil-based vitrimer: stoichiometric calculations, curing agent functionalities and catalyst efficiency.Royal Society open science · 2025Review
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Thermosets are valued for their exceptional dimensional stability, mechanical properties, and resistance to creep and chemicals. Their permanent molecular structures limit reshaping, reprocessing, and recycling. Incorporating exchangeable chemical bonds into cross-linked polymer networks provides materials with thermoset-like properties that are also reprocessable. Here, ring-opening copolymerization (ROCOP) of unpurified, commercially available epoxides and succinic anhydride is employed to synthesize well-defined, low molecular weight polyesters with controlled functionalization. Polymer networks are then formed through the catalyzed reaction of these copolymers with the epoxy-containing cross-linker diglycidyl ether of bisphenol A. Catalyst mixtures of zinc bis(2-ethylhexanoate) and 1,8-diazabicyclo(5.4.0)undec-7-ene are used to assess the role of the catalysts in the curing and dynamic bond exchange reactions. Varying the catalyst ratios results in polymer networks with tunable mechanical properties (90% < ε
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.