ArticleNature communications2025
Highly porous metal-organic framework glass design and application for gas separation membranes.
Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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The trial behind it
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Who cites it
9 citing papers in PubMed.
- Polymer-Grafted Cu(II) Metal-Organic Polyhedra as Scalable, Melt-Processable Porous Materials.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Carboxylate-Ligand-Based Coordination Polymers and Metal Complexes: From Structural Diversity and Supramolecular Descriptors to Function-Oriented Design.Molecules (Basel, Switzerland) · 2026Review
- Flux-mediated ligand exchange restructures metal-organic framework glasses.Nature materials · 2026Article
- Regulating the microporous structure by cavity-shaped molecular sieving channels.Science advances · 2026Article
- Melt-sintering of MOF glass-2D nanosheet composites for enhanced processability and gas separation performance.Chemical science · 2026Article
- Nanographene-Based van der Waals Organic Framework With Permanent Porosity.Angewandte Chemie (International ed. in English) · 2026Article
- MOF gel network crosslinked mixed matrix membranes with engineered interface for high-efficiency Helium recovery.Nature communications · 2026Article
- Unlocking large-area free-standing MOF-glasses for molecular sieving gas separation membranes.Nature communications · 2026Article
- Crystal Surface Reactivity of Esterase@Zeolitic Imidazolate Framework Biocomposites.Journal of the American Chemical Society · 2026Article
Corrections and comments
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Authors and funding
13 authors.
Funding
Abstract
Crystalline metal-organic frameworks (MOFs) exhibit enormous potential application in gas separation, thanks to their highly porous structures and precise pore size distributions. Nevertheless, the inherent limitations in mechanical stability of crystalline MOFs cause challenges in processing MOF powders into bulky structures, particularly for membrane filtrations. Melt-quenched MOF glasses boast excellent processability due to liquid-like properties. However, the melting process diminishes the inherent porosity, leading to reduced gas adsorption capacities and lower gas diffusion coefficients. In this work, we demonstrated that enhancing the porosity of MOF glasses is achievable through topological engineering on the crystalline precursors. Crystalline zeolitic imidazolate frameworks (ZIFs) with large 12-membered rings pores, including AFI and CAN topology, were synthesized by using both structure-directing agents and mixed organic ligands. The large pores are partially preserved in the melt-quenched glass as evidenced by high-pressure CO
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.