ArticleMaterials (Basel, Switzerland)2025
Insights into HKUST-1 Metal-Organic Framework's Morphology and Physicochemical Properties Induced by Changing the Copper(II) Salt Precursors.
Article in Materials (Basel, Switzerland), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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2 citing papers in PubMed.
- Cu-based metal-organic frameworks: synthesis, biomedical applications, and beyond.Discover nano · 2026Review
- Cascaded, self-decomposing messenger in MXene@Cu-MOF heterostructures for on-demand infection control and pro-angiogenic wound repair.Materials today. Bio · 2026Article
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6 authors.
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Abstract
The HKUST-1 metal-organic framework was synthesized using four different copper(II) salt precursors, namely copper nitrate, copper sulphate, copper acetate, and copper chloride, via the solvothermal method with no mixing. Syntheses were conducted without using the N,N-dimethylformamide to allow for a greener synthesis of MOFs. The selected physicochemical properties of the obtained metal-organic frameworks were determined. The yield of the obtained products changed in the order acetate>nitrate>sulfate, while no product was obtained in the synthesis with copper(II) chloride. The obtained materials were characterized by means of XRD, nitrogen adsorption-desorption at -196 °C, FTIR, XPS, TGA, SEM, and DLS. The morphology of crystallites and their physicochemical properties were significantly affected when different copper(II) salt precursors were used. The comparison of the obtained results with already published works allows for the correlation of the synthesis parameters like synthesis temperature, time, mixing, and copper(II) salt precursor used on selected properties of the final product.
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