Exploring the Synergistic Effect of Short Aramid Fibers and Graphene Nanoplatelets on the Mechanical and Dynamic Mechanical Properties of Polypropylene Composites Prepared via Thin-Plate Injection.

The present study aims to evaluate thin plate-injected polypropylene (PP) composites containing short aramid fibers (AF) and graphene nanoplatelets (GNPs). The aramid fibers were manually cut to a length of 10 mm and added to the polypropylene matrix at a concentration of 10 wt.%. Additionally, GNPs were incorporated at concentrations of 0.1, 0.25, and 0.5 wt.%. Maleic anhydride grafted polypropylene (MAPP) was used at a concentration of 2 wt.% to improve the adhesion and compatibility between the polymer matrix and the fillers. Thermal analyses, tensile and flexural tests, and dynamic mechanical thermal analysis were performed, followed by statistical analysis using ANOVA and Tukey's test. The composites demonstrated significant improvements in storage and loss moduli compared to neat polypropylene. With the addition of AF and GNPs, tensile strength increased to 46.8 MPa, which represents a 265% enhancement compared to PP. Similarly, flexural strength reached 62.4 MPa, significantly higher than the 36.73 MPa for PP, particularly for the composite containing AF and 0.25 wt.% GNPs. The results presented in this study highlight the synergistic effect of aramid fibers and GNPs on PP. These improvements make the proposed composites highly promising for a range of applications, including ballistic interlayered aramid/thin-plate laminates.