ReviewNanomaterials (Basel, Switzerland)2025
Boron Nitride-Supported Metal Catalysts for the Synthesis and Decomposition of Ammonia and Formic Acid.
Review in Nanomaterials (Basel, Switzerland), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
This review explores the recent advancements in the application of boron nitride (BN) as a support material for metallic nanoparticles, highlighting its potential in fostering sustainable chemical reactions when employed as a heterogeneous catalyst. Two key processes, both critical to hydrogen storage and transport, are examined in detail. First, the reversible synthesis and decomposition of ammonia using BN-supported metallic catalysts has emerged as a promising technology. This approach facilitates the preparation of Ru nanoparticles with precisely structured surface atomic ensembles, such as B5 sites, which are critical for maximizing catalytic efficiency. Second, the review emphasizes the role of BN-supported catalysts in the production of formic acid (FA), a process intrinsically linked to the reuse of carbon dioxide. In this context, hydrogen and carbon dioxide-potentially sourced from atmospheric capture-serve as reactants. BN's high CO
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