Evidence map›Paper›PMID 39932156›Full record

ArticleJournal of the American Chemical Society2025

Ze-Jie Lv, Arnd Fitterer, Regine Herbst-Irmer, Serhiy Demeshko, Hendrik Verplancke, Max C Holthausen, Sven Schneider

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed.

  1. Solid-state molecular organometallic chemistry (SMOM): a user guide toDalton transactions (Cambridge, England : 2003) · 2026
    Review
  2. Article
  3. Gold(III)-Substituted Carbenes.Journal of the American Chemical Society · 2026
    Article
  4. Article
  5. The Genuine Carbene Conundrum.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025
    Review
  6. ACS central science · 2025
    Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Ze-Jie LvInstitut für Anorganische Chemie and International Center for Advanced Studies of Energy Conversion (ICASEC), University of Göttingen, Tammannstraße 4, 37077 Göttingen, Germany.ORCID 0000-0003-1994-8400
Arnd FittererInstitut für Anorganische und Analytische Chemie, Goethe-Universität, Max-von-Laue-Straße 7, 60438 Frankfurt am Main, Germany.
Regine Herbst-IrmerInstitut für Anorganische Chemie and International Center for Advanced Studies of Energy Conversion (ICASEC), University of Göttingen, Tammannstraße 4, 37077 Göttingen, Germany.
Serhiy DemeshkoInstitut für Anorganische Chemie and International Center for Advanced Studies of Energy Conversion (ICASEC), University of Göttingen, Tammannstraße 4, 37077 Göttingen, Germany.
Hendrik VerplanckeInstitut für Anorganische und Analytische Chemie, Goethe-Universität, Max-von-Laue-Straße 7, 60438 Frankfurt am Main, Germany.
Max C HolthausenInstitut für Anorganische und Analytische Chemie, Goethe-Universität, Max-von-Laue-Straße 7, 60438 Frankfurt am Main, Germany.ORCID 0000-0001-7283-8329
Sven SchneiderInstitut für Anorganische Chemie and International Center for Advanced Studies of Energy Conversion (ICASEC), University of Göttingen, Tammannstraße 4, 37077 Göttingen, Germany.ORCID 0000-0002-8432-7830

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The Wolff rearrangement (WR) is widely used for the synthesis of ketenes from diazoketones and -esters. Stepwise WR reactions are proposed to proceed through transient carbonylcarbene (R-C-C(O)-R') intermediates, which so far have evaded structural characterization. Here, a Wolff metallocarbene (Pt

Identifiers

PMID39932156
PMCPMC11848915

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.